(+)-3-carene

Base Information

• Chemical Name: (+)-3-carene
• CAS No.: 19079-29-9
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 136.237
• Mol file: 19079-29-9.mol

Synonyms:

Chemical Property of (+)-3-carene

Chemical Property:

• Vapor Pressure: 1.86mmHg at 25°C
• Water Solubility.: <0.1 g/100 mL at 22 C

Purity/Quality:

Safty Information:

• Hazard Codes: Xi:Irritant;; <
• Statements: R10:; R50/53:
• Safety Statements: S36/37:; S60:; S61:

MSDS Files:

Useful:

Technology Process of (+)-3-carene

There total 24 articles about (+)-3-carene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

C30H45BO → (+)-Δ3-carene (498-15-7,19079-29-9) + (S)-1-Phenyl-3-buten-1-ol (77118-87-7,936-58-3)

Guidance literature:

With boron trifluoride diethyl etherate; isobutyraldehyde; at 65 ℃; for 48h;

DOI:10.1021/jo00050a044

Reference yield: 65.0%

3-carene epoxide (936-91-4) → (+)-Δ3-carene (498-15-7,19079-29-9)

Guidance literature:

With dimethyl diazomalonate; chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]copper(I); In toluene; for 4h; Reagent/catalyst; stereospecific reaction; Sealed tube; Reflux;

DOI:10.1021/acs.orglett.6b02405

Reference yield: 27.1%

3,7,7-trimethyl-cyclohepta-1,3,5-triene (3479-89-8) → 1,4,4-trimethylcycloheptane (2158-55-6) + 2-carene (554-61-0) + 1,5,5-trimethylcycloheptene (7348-54-1) + 1,4,4-trimethylcycloheptene (4755-36-6) + carane (554-59-6) + 3-carene (13466-78-9,19079-29-9)

Guidance literature:

With hydrogen; platinum; In hexane; at 20 - 22 ℃; Product distribution; various amounts of hydrogen;

DOI:10.1007/BF00575696

upstream raw materials:

2-carene

carbon monoxide

α-terpinylphenylsulphide

methyllithium

Downstream raw materials:

8-hydroxy-m-cymene

(5S)-(-)-5β-(1-Hydroxy-1-methylethyl)-1-methyl-1,3-cyclohexadien

3-caren-9-ol

3-carene-10-carboxylic acid