dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

Base Information

• Chemical Name: dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate
• CAS No.: 99299-52-2
• Molecular Formula: C₄₅H₄₄O₂P₃Ru*F₆P
• Molecular Weight: 955.799
• Mol file: 99299-52-2.mol

Synonyms:

Chemical Property of dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

There total 1 articles about dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

sodium hexaflorophosphate + dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) + ethyl iodide (75-03-6) → dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99299-52-2) + diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (99299-46-4)

Guidance literature:

With trimethylamine N-oxide; In ethanol; dichloromethane; under N2, EtI added to Ru(CO)2(triphos) in CH2Cl2, stirred at room temp. for 5 h, evapd. in vac., taken up in EtOH, RuI2(CO)(triphos) filtered off, Me3NO added to mixt. in CH2Cl2, evapd., dissolved in EtOH, filtered, treated with NaPF6 in EtOH; ppt. collected, washed with EtOH and Et2O, dried at room temp.; elem. anal.;

upstream raw materials:

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽⁰⁾

ethyl iodide