Technology Process of Lithium bismuthide (Li3Bi)
There total 4 articles about Lithium bismuthide (Li3Bi) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
melt;
Li, washed with benzene and dried in high vaccum, is mixed with stoichiometric amount of Bi under Ar or Bi; molten together in a closed Fe-vessel at 515°C;;
- Guidance literature:
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In
neat (no solvent);
two-source vac. evapn. of Bi and Li in glove box onto substrate (quartz plate at < 390 K) under Ar or N2, humidity held at < 10 ppm H2O vapour, to produce thin films 1.5-3.0 μm thick in 30 min of evapn., subsequent annealing (620 K, 12h), cooling; chem. compn. of film determined by ICPS showed varying amts. of Li3Bi, LiBi and Bi depending on the Li concn.;
DOI:10.1016/0025-5408(88)90184-5
- Guidance literature:
-
In
neat (no solvent);
byproducts: H2; grinding Bi and 10-15% excess LiH, heating (402°C); X-ray powder diffraction analysis;
