aluminum trichloride tetrahydrofuran complex

Base Information

• Chemical Name: aluminum trichloride tetrahydrofuran complex
• CAS No.: 15283-71-3
• Molecular Formula: C₄H₈AlCl₃O
• Molecular Weight: 205.447
• Mol file: 15283-71-3.mol

Synonyms:

Chemical Property of aluminum trichloride tetrahydrofuran complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of aluminum trichloride tetrahydrofuran complex

There total 5 articles about aluminum trichloride tetrahydrofuran complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Al12(AlCl2(C4H8O))10(C4H8O)2 → AlCl3*THF (192656-42-1,15283-71-3) + aluminium (7429-90-5)

Guidance literature:

In neat (no solvent); heating above 100°C;

DOI:10.1021/ja004022x

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + aluminium trichloride (7446-70-0) → AlCl3*THF (192656-42-1,15283-71-3)

Guidance literature:

In toluene; (N2); slow addn. of THF to suspn. of AlCl3 in toluene at -30°C; heating at room temp.; removal of solvent in vac.;

DOI:10.1021/om0492496

Reference yield:

isobutyl aluminum dichloride → aluminum trichloride tetrahydrofuran complex (15283-71-3,192656-42-1)

Guidance literature:

With tetrahydrofuran; In hexane; a hexane soln. of isobutyl aluminum dichloride and THF were mixed in 1:0.5 ratio and cooled to -20°C;; ppt.; washed with hexane and dried under vac.; elem. anal.;;

upstream raw materials:

tetrahydrofuran

aluminium trichloride

[PrCl(μ-Cl)2(tetrahydrofuran)2]n

ethylaluminum dichloride

Downstream raw materials:

(2,4,6-t-Bu₃C₆H₂)AlCl₂