Ir(O₂)I(CS)(PPh₃)2

Base Information

Chemical Name:Ir(O₂)I(CS)(PPh₃)2
CAS No.:936944-31-9
Molecular Formula:CH₂Cl₂*C₃₇H₃₀IIrO₂P₂S
Molecular Weight:1004.71
Hs Code.:

Ir(O<sub>2</sub>)I(CS)(PPh<sub>3</sub>)2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ir(O₂)I(CS)(PPh₃)2

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Technology Process of Ir(O₂)I(CS)(PPh₃)2

There total 1 articles about Ir(O₂)I(CS)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 75-09-2
dichloromethane

: 936944-23-9
IrI(CS)(PPh₃)2

: 80937-33-3
oxygen

: 936944-31-9
Ir(O₂)I(CS)(PPh₃)2

Guidance literature:: In dichloromethane; soln. Ir complex in CH2Cl2 was stirred in air for 1 h; EtOH was added, CH2Cl2 was removed in vacuo; elem. anal.;
DOI:10.1021/om061066r

Reference yield: 56.0%

: 75-09-2
dichloromethane

: 936944-31-9
Ir(O₂)I(CS)(PPh₃)2

: 74-86-2,25067-58-7
acetylene

: Ir[C₃H₂(CH=CHS-1)]I(PPh₃)2*CH₂Cl₂

Guidance literature:: In benzene; High Pressure; soln. Ir complex in benzene in Fisher-Porter bottle was subjected to ethyne (20 psi) and heated to 75°C for 21 h; solvent was removed in vacuo, residue was recrystd. from CH2Cl2 and EtOH; elem. anal.;
DOI:10.1021/om061066r

Reference yield: 36.0%

: 64-17-5
ethanol

: 75-09-2
dichloromethane

: 936944-31-9
Ir(O₂)I(CS)(PPh₃)2

: 536-74-3
phenylacetylene

: Ir[η5-C5H2(SCPh=CH-1)(Ph-3)(Ph-5)]Cl(PPh3)*CH2Cl2

: Ir[C₃H(CH=C(Ph)S-1)(Ph-3)]Cl(PPh₃)2*CH₂Cl₂

: Ir[C₃H(CH=C(Ph)S-1)(Ph-2)]Cl(PPh₃)2*CH₂Cl₂*C₂H₅OH

Guidance literature:: In benzene; suspn. Ir complex and phenylacetylene in benzene was heated under refluxfor 6 h; solvent was removed in vacuo, residue was recrystd. from CH2Cl2 and heptane followed by recrystn. from CH2Cl2 and EtOH; elem. anal.;
DOI:10.1021/om061066r