(pentamethylcyclopentadienyl)2Zr(C₆H₅)F

Base Information

Chemical Name:(pentamethylcyclopentadienyl)2Zr(C₆H₅)F
CAS No.:383862-20-2
Molecular Formula:C₂₆H₃₅FZr
Molecular Weight:457.786
Hs Code.:

(pentamethylcyclopentadienyl)2Zr(C<sub>6</sub>H<sub>5</sub>)F

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (pentamethylcyclopentadienyl)2Zr(C₆H₅)F

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Technology Process of (pentamethylcyclopentadienyl)2Zr(C₆H₅)F

There total 4 articles about (pentamethylcyclopentadienyl)2Zr(C₆H₅)F which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: (η(5)-C5Me5)2ZrF2

: 591-51-5
phenyllithium

: 383862-20-2
(pentamethylcyclopentadienyl)2Zr(C₆H₅)F

Guidance literature:: In toluene; under N2; Zr complex and phenyllithium were added and suspended in toluene, the mixt. was freeze-pump-thawed and heated to 85°C for 5 h with stirring; the mixt. was stripped to dryness, pentane was added, the mixt. was filtered over Celite, concd. and recrystd. at -30°C;
DOI:10.1021/ja016087l

Reference yield:

: 462-06-6
fluorobenzene

: 61396-34-7
(pentamethylcyclopentadienyl)2ZrH₂

: 383862-20-2
(pentamethylcyclopentadienyl)2Zr(C₆H₅)F

: 87985-79-3
[(η(5)-pentamethylcyclopentadienyl)2ZrHF]

Guidance literature:: With H₂; 1,2,4,5-tetramethylbenzene; In Cyclohexane-d12; byproducts: benzene; under N2; a NMR tube was charged with Zr complex in C6((2)H)12, fluorobenzene was added via syringe, the tube was freeze-pump-thaw degassed 3 times and H2 was added, the tube was heated at 85°C for 40 d; C6H2(CH3)4 had no effect on the react.; not isolated, monitored by NMR;
DOI:10.1021/ja016087l

Reference yield:

: 383862-18-8
(pentamethylcyclopentadienyl)2Zr(C₆H₄F)H

: 383862-20-2
(pentamethylcyclopentadienyl)2Zr(C₆H₅)F

Guidance literature:: In Cyclohexane-d12; under N2; a soln. of Zr complex in cyclohexane-d12 was heated at 80°C for 18 d; the volatiles were removed in vac., the residue was recrystd. in pentaneat -30°C ; elem. anal.;
DOI:10.1021/ja016087l