[Cp₂ZrCH₂NMePh][B(C₆F₅)₄]

Base Information

• Chemical Name: [Cp₂ZrCH₂NMePh][B(C₆F₅)₄]
• CAS No.: 511512-82-6
• Molecular Formula: C₁₈H₂₀NZr*C₂₄BF₂₀
• Molecular Weight: 1020.63

Synonyms:

Chemical Property of [Cp₂ZrCH₂NMePh][B(C₆F₅)₄]

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Technology Process of [Cp₂ZrCH₂NMePh][B(C₆F₅)₄]

There total 2 articles about [Cp₂ZrCH₂NMePh][B(C₆F₅)₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(cyclopentadienyl)dimethylzirconium(IV) (12636-72-5) + N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate → [Cp2ZrCH2NMePh][B(C6F5)4] (511512-82-6)

Guidance literature:

In benzene-d6; (N2); Schlenk line; B compd. and Zr complex were dissolved in C6D6 in NMR tube; shaken for few min; supernatant removed; residue rinsed with C6H6; after 5 h solvent removed(vac.);

DOI:10.1021/om100827z

Reference yield:

bis(cyclopentadienyl)dimethylzirconium(IV) (12636-72-5) + (Me2Al(μ-OSiMe2C(CH3)3)2AlMeNMe2Ph)(B(C6F5)4) (511512-70-2) → Me2Al(μ-OSiMe2C(CH3)3)2AlMe2 (511512-66-6) + [Cp2ZrCH2NMePh][B(C6F5)4] (511512-82-6)

Guidance literature:

In benzene-d6; byproducts: CH4; (Ar); using Schlenk techniques; sealing of NMR tube with stock soln. of (((t-Bu)Me2SiO)2Al2Me3NMe2Ph)(B(C6F5)4) and Cp2ZrMe2 in C6D6 at room temp.; keeping at -80°C until the first meausurement; heating to 300K; monitoring by NMR;

DOI:10.1021/om0207515

Reference yield:

[Cp2ZrCH2NMePh][B(C6F5)4] (511512-82-6) + hydrogen (1333-74-0) → C30H34Zr3(2+)*2C24BF20(1-)

Guidance literature:

at 20 ℃; for 24h; under 760.051 Torr; Schlenk technique; Sealed tube;

DOI:10.1039/c9cc09466k

upstream raw materials:

bis(cyclopentadienyl)dimethylzirconium(IV)

(Me2Al(μ-OSiMe2C(CH3)3)2AlMeNMe2Ph)(B(C6F5)4)

Downstream raw materials:

Zr(C₅H₅)2(CH₂C(CH₃)(C₅H₁₁)CH₂N(CH₃)(C₆H₅))⁽¹⁺⁾*B(C₆F₅)4^(1-)=[Zr(C₅H₅)2(CH₂C(CH₃)(C₅H₁₁)CH₂N(CH₃)(C₆H₅))][B(C₆F₅)4]

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