{(dppe)(η-C6H6)ReH}

Base Information

Chemical Name:{(dppe)(η-C6H6)ReH}
CAS No.:142196-02-9
Molecular Formula:C₃₂H₃₁P₂Re
Molecular Weight:663.753
Hs Code.:

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Chemical Property of {(dppe)(η-C6H6)ReH}

Chemical Property:

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Technology Process of {(dppe)(η-C6H6)ReH}

There total 2 articles about {(dppe)(η-C6H6)ReH} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 12101-19-8
1,2-bis(diphenylphosphino)ethane rhenium heptahydride

: 142196-02-9
{(dppe)(η-C6H6)ReH}

Guidance literature:: With cyclohexa-1,4-diene; In tetrahydrofuran; Irradiation (UV/VIS); a soln. of ((dppe)ReH7) and cyclohexa-1,4-diene in THF was irradiated (medium pressure Hg lamp, Hanau 450W) at 20 °C for 4 h, evaporation of the solvent;; residue dissolved in Et2O, addn. of HBF4*Et2O led to ((dppe)(C6H6)ReH2)(BF4), brown solid was filtered off, washed with Et2O, dried in vac. and dissolved in acetone, addn. of NaOMe in MeOH, evapn., to dryness, extn. with Et2O, evapn. gave a yellow oil;;
DOI:10.1016/0022-328X(92)80072-6

Reference yield:

: 142196-05-2
{(dppe)(η-C6H6)ReH2}{BF4}

: 142196-02-9
{(dppe)(η-C6H6)ReH}

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1016/0022-328X(92)80072-6

Reference yield: 98.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 142196-02-9
{(dppe)(η-C6H6)ReH}

: 142196-05-2
{(dppe)(η-C6H6)ReH2}{BF4}

Guidance literature:: In diethyl ether; HBF4*Et2O was added to a soln. of ((dppe)(C6H6)ReH) in Et2O, colorless microcrystals immediately deposited, these were filtered off;; washed with Et2O, dried under vacuum; elem. anal.;;
DOI:10.1016/0022-328X(92)80072-6