ReOCl₂(OC₂H₅)(P(C₆H₅)3)2

Base Information

Chemical Name:ReOCl₂(OC₂H₅)(P(C₆H₅)3)2
CAS No.:17442-19-2
Molecular Formula:C₃₈H₃₅Cl₂O₂P₂Re
Molecular Weight:842.755
Hs Code.:

ReOCl<sub>2</sub>(OC<sub>2</sub>H<sub>5</sub>)(P(C<sub>6</sub>H<sub>5</sub>)3)2

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ReOCl₂(OC₂H₅)(P(C₆H₅)3)2

Chemical Property:

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Technology Process of ReOCl₂(OC₂H₅)(P(C₆H₅)3)2

There total 3 articles about ReOCl₂(OC₂H₅)(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: ammonium perrhenate

: 64-17-5
ethanol

: 603-35-0
triphenylphosphine

: 17442-19-2,80227-22-1
dichlorooxoethoxobis(triphenylphosphine)rhenium(V)

Guidance literature:: In ethanol; excess HCl, refluxing for 10 min; cooling to room temp., collection (filtration), washing (EtOH, Et2O);
DOI:10.1016/S0020-1693(96)05537-5

Reference yield:

: ammonium perrhenate

: 17442-19-2,80227-22-1
dichlorooxoethoxobis(triphenylphosphine)rhenium(V)

Guidance literature:: With P(C₆H₅)3; ethanol; HCl; In hydrogenchloride; ethanol; suspending perrhenate in concd. HCl; addn. to PPh3 soln. in ethanol; refluxing, 10 min; filtration; washing (ethanol, ethyl ether); drying;
DOI:10.1016/S0020-1693(00)87352-1

Reference yield:

: 7647-01-0,15364-23-5
hydrogenchloride

: rhenium

: 64-17-5
ethanol

: 7722-84-1
dihydrogen peroxide

: 603-35-0
triphenylphosphine

: 17442-19-2,80227-22-1
dichlorooxoethoxobis(triphenylphosphine)rhenium(V)

Guidance literature:: In dihydrogen peroxide; N.P. Johnson et al., J. Chem. Soc. 1964, Re metal dissolved in 30% H2O2,concd., HCl and EtOH added, refluxed, hot EtOH soln. of PPh3 added; pptd., septd.;
DOI:10.1134/S1070328412030037