Mn(CO)4(P(C₆H₁₁)3)Cl

Base Information

• Chemical Name: Mn(CO)4(P(C₆H₁₁)3)Cl
• CAS No.: 14219-83-1
• Molecular Formula: C₂₂H₃₃ClMnO₄P
• Molecular Weight: 482.866
• Mol file: 14219-83-1.mol

Synonyms:

Chemical Property of Mn(CO)4(P(C₆H₁₁)3)Cl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Mn(CO)4(P(C₆H₁₁)3)Cl

There total 3 articles about Mn(CO)4(P(C₆H₁₁)3)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentacarbonylchloromanganese(I) (14100-30-2) → Mn(CO)3(P(C6H11)3)2Cl + Mn(CO)4(P(C6H11)3)Cl (14219-83-1)

Guidance literature:

With tricyclohexylphosphine; In not given; byproducts: CO; Irradiation (UV/VIS); N2 atmosphere, excess phosphine in soln., photolysis (200-W high-pressure Hg arc lamp, Corning cutoff filters, λ>250 nm); not isolated, IR detection;

Reference yield:

1,2-diax-Mn2(CO)8(P(C6H11)3)2 → Mn(CO)4(P(C6H11)3)Cl (14219-83-1)

Guidance literature:

With tetrachloromethane; Irradiation (UV/VIS); flash photogeneration of Mn(CO)4P(C6H11)3 radicals from Mn2(CO)8(P(C6H11)3)2 in the presence more then a tenfold excess of CCl4; measured by using xenon lamp flash photolysis apparatus, 24°C; Kinetics;

DOI:10.1021/om00120a008

Reference yield:

Mn2*8CO*2P(C6H11)3=Mn2(CO)8(P(C6H11)3)2 + 1,1,2,2-tetrachloroethane (79-34-5) → Mn(CO)4(P(C6H11)3)Cl (14219-83-1)

Guidance literature:

In decalin; byproducts: PCy3; 40°C; not isolated, reaction followed by IR-spectroscopy; Kinetics;

DOI:10.1039/c39830000566

upstream raw materials:

pentacarbonylchloromanganese(I)

1,1,2,2-tetrachloroethane