[Ni(II)(salicylaldehyde oximate)2]

Base Information

• Chemical Name: [Ni(II)(salicylaldehyde oximate)2]
• CAS No.: 54515-04-7
• Molecular Formula: C₁₄H₁₂N₂NiO₄
• Molecular Weight: 330.95
• Mol file: 54515-04-7.mol

Synonyms:

Chemical Property of [Ni(II)(salicylaldehyde oximate)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(II)(salicylaldehyde oximate)2]

There total 3 articles about [Ni(II)(salicylaldehyde oximate)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(N-ethylsalicylaldiminato)nickel(II) (35968-61-7,13987-25-2,35672-82-3) + hydroxylamine hydrochloride (5470-11-1) → [Ni(II)(salicylaldehyde oximate)2] (54515-04-7,50897-08-0,14363-30-5) + ethanamine hydrochloride (557-66-4)

Guidance literature:

In methanol; stirring the soln. for 30 min between room temp. and 60°C, pptn.; filtration, washing with water, recrystn. from acetone;

DOI:10.1016/S0020-1693(00)83239-9

Reference yield: 90.0%

bis(N-(n-butyl)salicylaldiminato)nickel(II) (1091611-04-9,35594-78-6,13986-36-2) + hydroxylamine hydrochloride (5470-11-1) → [Ni(II)(salicylaldehyde oximate)2] (54515-04-7,50897-08-0,14363-30-5) + n-butylamine hydrochloride (3858-78-4)

Guidance literature:

In methanol; stirring the soln. for 30 min between room temp. and 60°C, pptn.; filtration, washing with water, recrystn. from acetone;

DOI:10.1016/S0020-1693(00)83239-9

Reference yield: 90.0%

[Ni(OC6H4CHNC6H5)2] (38929-70-3,14266-60-5) + hydroxylamine hydrochloride (5470-11-1) → [Ni(II)(salicylaldehyde oximate)2] (54515-04-7,50897-08-0,14363-30-5) + aniline hydrochloride (142-04-1,36663-09-9)

Guidance literature:

In methanol; stirring the soln. for 30 min between room temp. and 60°C, pptn.; filtration, washing with water, recrystn. from acetone;

DOI:10.1016/S0020-1693(00)83239-9

upstream raw materials:

bis(N-(n-butyl)salicylaldiminato)nickel(II)

hydroxylamine hydrochloride

bis(N-ethylsalicylaldiminato)nickel(II)

[Ni(OC₆H₄CHNC₆H₅)2]

Downstream raw materials:

hydroxylamine hydrochloride

nickel(II)

salicylaldehyde 2,4-dinitrophenylhydrazone

salicylaldehyde-oxime