{RuHCl(triphenylphosphine)3} * benzene

Base Information

Chemical Name:{RuHCl(triphenylphosphine)3} * benzene
CAS No.:22493-02-3
Molecular Formula:C₆H₆*C₅₄H₄₆ClP₃Ru
Molecular Weight:1002.52
Hs Code.:

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Chemical Property of {RuHCl(triphenylphosphine)3} * benzene

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Technology Process of {RuHCl(triphenylphosphine)3} * benzene

There total 2 articles about {RuHCl(triphenylphosphine)3} * benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15529-49-4,41756-81-4
dichlorotris(triphenylphosphine)ruthenium(II)

: 1333-74-0
hydrogen

: 22493-02-3,51383-67-6
{RuHCl(triphenylphosphine)3} * benzene

Guidance literature:: With triethylamine; In benzene; byproducts: (C2H5)3NHCl; passing H2 through soln. of RuCl2(C18H15P)3 in degassed benzene at 25°C for 12 to 15 h, concentrating filtrate with stirring, washing with ethanol and ether;; drying and storing in vacuum;;
DOI:10.1039/C19670000305

Reference yield:

: 16940-66-2
sodium tetrahydroborate

: 15529-49-4,41756-81-4
dichlorotris(triphenylphosphine)ruthenium(II)

: 22493-02-3,51383-67-6
{RuHCl(triphenylphosphine)3} * benzene

Guidance literature:: In water; benzene; boiling for 1 h with reflux and passing H2 or N2 through soln., crystallizes in several days from oversaturated soln.,; washing with degassed ether (free from peroxides), drying and storing in vacuum;;
DOI:10.1039/C19670000305

Reference yield: 90.0%

: 22493-02-3,51383-67-6
chlorohydridotris(triphenylphosphine)ruthenium * benzene

: 1333-74-0
hydrogen

: 114595-94-7
RuH₂(H₂)(PPh₃)3

Guidance literature:: With sodium hydroxide; In benzene; byproducts: HCl; mixt. of Ru-complex, triethylbenzylammonium chloride, benzene and 50% NaOH vigorously stirred under H2 (1 atm, 20°C, until the red purple color disappeared (1-2 h)),; isolation under Ar, slurry diluted with H2 saturated MeOH, pptn., filtration, washed (degassed MeOH, 2 times; degassed pentane 3 times), evapn.;
DOI:10.1016/0022-328X(90)85226-O