{RhH₂(CO)(triphos)}PF₆

Base Information

Chemical Name:{RhH₂(CO)(triphos)}PF₆
CAS No.:121374-19-4
Molecular Formula:C₄₂H₄₁OP₃Rh*F₆P
Molecular Weight:902.578
Hs Code.:

{RhH<sub>2</sub>(CO)(triphos)}PF<sub>6</sub>

Synonyms:

Suppliers and Price of {RhH₂(CO)(triphos)}PF₆

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {RhH₂(CO)(triphos)}PF₆

Chemical Property:

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Technology Process of {RhH₂(CO)(triphos)}PF₆

There total 1 articles about {RhH₂(CO)(triphos)}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 75070-58-5
{Rh(CO)2(triphos)}PF₆

: 1333-74-0
hydrogen

: 121374-19-4
{RhH₂(CO)(triphos)}PF₆

Guidance literature:: In tetrahydrofuran; byproducts: CO; H2 (50 atm) pressed into soln. of complex (minireactor, room temp.), temp. raised to 50°C (P=68 atm), after 18 h 0f react. H2 vented; mixture with 40% starting material no react. at 1 atm H2/RT; solvent removed (vac.), residue dried (vac.); detn. by 31P NMR;
DOI:10.1021/om00110a011

Reference yield: 85.0%

: 121374-19-4
{RhH₂(CO)(triphos)}PF₆

: 74-85-1
ethene

: 121374-30-9
{Rh(CO)(ethylene)(triphos)}PF₆

Guidance literature:: In tetrahydrofuran; byproducts: H2; ethylene bubbled through soln. of complex (N2, 20-40 min); pptd. filtered, washed with THF, dried (vac.); elem. anal.;
DOI:10.1021/om00110a011

Reference yield: 80.0%

: 121374-19-4
{RhH₂(CO)(triphos)}PF₆

: 603-35-0
triphenylphosphine

: 121393-32-6
{Rh(CO)(PPh₃)(triphos)}PF₆

Guidance literature:: In tetrahydrofuran; byproducts: H2; phosphine added to soln. of complex (N2, room temp.); ppt. filtered, washed with THF, dried (vac.); elem. anal.;
DOI:10.1021/om00110a011