cis-di(chloro)(tetraphenylporphyrinato^(2-))zirconium(IV)

Base Information

Chemical Name:cis-di(chloro)(tetraphenylporphyrinato^(2-))zirconium(IV)
CAS No.:77370-96-8
Molecular Formula:C₄₄H₂₈Cl₂N₄Zr
Molecular Weight:774.863
Hs Code.:

cis-di(chloro)(tetraphenylporphyrinato<sup>(2-)</sup>)zirconium(IV)

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Chemical Property of cis-di(chloro)(tetraphenylporphyrinato^(2-))zirconium(IV)

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Technology Process of cis-di(chloro)(tetraphenylporphyrinato^(2-))zirconium(IV)

There total 3 articles about cis-di(chloro)(tetraphenylporphyrinato^(2-))zirconium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: bis(acetato-O,O')[5,10,15,20-tetraphenyl-21H,23H-porphinato^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zirconium

: 77370-96-8
dichloro(5,10,15,20-tetraphenylporphyrinato) zirconium(IV)

Guidance literature:: In dichloromethane; N2-atmosphere; bubbling HCl through Zr-complex soln. for 30 min; concn., addn. of HCl satd. hexanes (pptn.), filtration, washing (hexanes), drying (50°C, 0.05 mm Hg, overnight);
DOI:10.1016/0022-328X(95)05835-D

Reference yield: 83.0%

: 21959-01-3,125410-70-0,125410-71-1
zirconium tetrachloride bis(tetrahydrofuran) complex

: 2Li⁽¹⁺⁾*N₄C₂₀H₈(C₆H₅)4^(2-)=Li₂(N₄C₂₀H₈(C₆H₅)4)

: 77370-96-8
dichloro(5,10,15,20-tetraphenylporphyrinato) zirconium(IV)

Guidance literature:: In toluene; mixt. refluxed under inert atm. for 2 h; monitored by UV-vis and TLC, filtered, washed with CH2Cl2, concd., cooled at -20°C overnight, filtered, washed with hexane, dried under vac.; elem. anal.;

Reference yield: 60.0%

: 917-23-7,20998-75-8
5,10,15,20-tetraphenyl-21H,23H-porphine

: 10026-11-6
zirconium(IV) chloride

: 77370-96-8
dichloro(5,10,15,20-tetraphenylporphyrinato) zirconium(IV)

Guidance literature:: In benzonitrile; soln. of ZrCl4 and porphyrin in benzonitrile refluxed for 1 h; evapn. under vac., residue dissolved in CHCl3, chromy. (alumina (activity II)), treatment with gaseous HCl;
DOI:10.1134/S1070363210040274