ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate

Base Information

• Chemical Name: ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate
• CAS No.: 97510-27-5
• Molecular Formula: C₁₂H₁₄O₂S₂
• Molecular Weight: 254.374
• Mol file: 97510-27-5.mol

Synonyms:

Chemical Property of ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate

There total 3 articles about ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(4-methoxyphenyl)ethanone (100-06-1) → ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate (97510-27-5)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium tert-butylate / diethyl ether / 3 h / -70 - 20 °C / Schlenk technique; Inert atmosphere

2: diethyl ether / 20 °C / Schlenk technique; Inert atmosphere

With potassium tert-butylate; In diethyl ether;

DOI:10.1039/c6dt01388k

Reference yield:

C10H9O2S2(1-)*K(1+) + ethyl iodide (75-03-6) → ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate (97510-27-5)

Guidance literature:

In diethyl ether; at 20 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1039/c6dt01388k

Reference yield:

→ ethyl β-oxo-β-(p-methoxyphenyl)dithioacetate (97510-27-5)

Guidance literature:

Acetophenon, 1. CS2, 2. Ethylierung;

upstream raw materials:

1-(4-methoxyphenyl)ethanone

ethyl iodide

Downstream raw materials:

1,5-bis(ethylthio)-2-(p-methoxybenzoyl)penta-1,3-diene

2-allyl-3,3-bis(ethylthio)-1-(p-methoxyphenyl)prop-2-en-1-one