RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2B(C₆H₃(CF₃)2)4

Base Information

• Chemical Name: RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2B(C₆H₃(CF₃)2)4
• CAS No.: 495389-62-3
• Molecular Formula: C₂₃H₃₄N₂O₂Rh*C₃₂H₁₂BF₂₄
• Molecular Weight: 1336.66
• Mol file: 495389-62-3.mol

Synonyms:

Chemical Property of RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2B(C₆H₃(CF₃)2)4

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2B(C₆H₃(CF₃)2)4

There total 1 articles about RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=RhCH₃C₆H(CH₃)2(CH₂C₃H₂NOC₃H₇H)2B(C₆H₃(CF₃)2)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

RhCF3SO3CH3C6H(CH3)2(CH2C3H2NOC3H7H)2 + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → RhCH3C6H(CH3)2(CH2C3H2NOC3H7H)2(1+)*B(C6H3(CF3)2)4(1-)=RhCH3C6H(CH3)2(CH2C3H2NOC3H7H)2B(C6H3(CF3)2)4 (495389-62-3)

Guidance literature:

In dichloromethane; Na-salt was added to soln. of Rh-complex in CH2Cl2 at ambient temp., stirred for 4 h at room temp. under Ar; filtered, solvent was removed under vac., triturated with pentane, solvent was removed under vac.; elem. anal.;

DOI:10.1021/om0207562

Reference yield: 97.0%

ethene (74-85-1) + RhCH3C6H(CH3)2(CH2C3H2NOC3H7H)2(1+)*B(C6H3(CF3)2)4(1-)=RhCH3C6H(CH3)2(CH2C3H2NOC3H7H)2B(C6H3(CF3)2)4 (495389-62-3) → RhC2H4CH3C6H(CH3)2(CH2C3H2NOC3H7H)2(1+)*B(C6H3(CF3)2)4(1-)=RhC2H4CH3C6H(CH3)2(CH2C3H2NOC3H7H)2B(C6H3(CF3)2)4

Guidance literature:

In dichloromethane; vessel was charged with Rh-complex and CH2Cl2, degassed, exposed to 70 mbar of C2H4, 14 h at room temp.; volatiles were removed under vac., triturated with pentane, solvent was removed under vac.; elem. anal.;

DOI:10.1021/om0207562

Reference yield: 96.0%

RhCH3C6H(CH3)2(CH2C3H2NOC3H7H)2(1+)*B(C6H3(CF3)2)4(1-)=RhCH3C6H(CH3)2(CH2C3H2NOC3H7H)2B(C6H3(CF3)2)4 (495389-62-3) + carbon monoxide (201230-82-2) → Rh(CO)2CH3C6H(CH3)2(CH2C3H2NOC3H7H)2(1+)*B(C6H3(CF3)2)4(1-)=Rh(CO)2CH3C6H(CH3)2(CH2C3H2NOC3H7H)2B(C6H3(CF3)2)4

Guidance literature:

In dichloromethane; NMR tube was charged with Rh-complex and CH2Cl2, degassed, exposed to 70mbar of CO, 14 h at room temp.; volatiles were removed under vac.; elem. anal.;

DOI:10.1021/om0207562

upstream raw materials:

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate