Au₄(C₃S₅)2(CH₂(P(C₆H₅)2)2)2*CH₃COCH₃

Base Information

• Chemical Name: Au₄(C₃S₅)2(CH₂(P(C₆H₅)2)2)2*CH₃COCH₃
• CAS No.: 156734-71-3
• Molecular Formula: C₃H₆O*C₅₆H₄₄Au₄P₄S₁₀
• Molecular Weight: 2007.47
• Mol file: 156734-71-3.mol

Synonyms:

Chemical Property of Au₄(C₃S₅)2(CH₂(P(C₆H₅)2)2)2*CH₃COCH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Au₄(C₃S₅)2(CH₂(P(C₆H₅)2)2)2*CH₃COCH₃

There total 3 articles about Au₄(C₃S₅)2(CH₂(P(C₆H₅)2)2)2*CH₃COCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[Au2(μ-2-thioxo-1,3-dithiole-4,5-dithiolate)(AsPh3)] + bis-diphenylphosphinomethane (2071-20-7) → Au4(C3S5)2(CH2(P(C6H5)2)2)2*CH3COCH3 (156734-71-3)

Guidance literature:

In acetone; to a suspn. of the complex in acetone was added the phosphine, stirred for 2 h; solvent was evapd., addn. of Et2O, filtered, washed with water;

DOI:10.1039/DT9940001325

Reference yield: 41.0%

(bis(diphenylphosphino)methane)bis(chlorogold(I)) (37095-27-5) + bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate (72022-68-5) → Au4(C3S5)2(CH2(P(C6H5)2)2)2*CH3COCH3 (156734-71-3)

Guidance literature:

In acetone; the gold complex was added to a soln. of the Zn compd. in acetone, stirred for 3 h; solvent was evapd., addn. of Et2O, filtered, washed with water; elem. anal.;

DOI:10.1039/DT9940001325

Reference yield:

(triphenylarsine)gold(I) chloride (25749-29-5) → Au4(C3S5)2(CH2(P(C6H5)2)2)2*CH3COCH3 (156734-71-3)

Guidance literature:

Multi-step reaction with 2 steps

1: acetone

2: acetone

In acetone;

DOI:10.1039/DT9940001325

upstream raw materials:

bis-diphenylphosphinomethane

(bis(diphenylphosphino)methane)bis(chlorogold(I))

bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate

(triphenylarsine)gold(I) chloride