((C₆H₅)2PCH₂CH₂P(C₆H₅)2)PtCl(CH(CH₃)CO₂C(CH₃)3)*CH₂Cl₂

Base Information

• Chemical Name: ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)PtCl(CH(CH₃)CO₂C(CH₃)3)*CH₂Cl₂
• CAS No.: 916769-16-9
• Molecular Formula: CH₂Cl₂*C₃₃H₃₇ClO₂P₂Pt
• Molecular Weight: 843.069
• Mol file: 916769-16-9.mol

Synonyms:

Chemical Property of ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)PtCl(CH(CH₃)CO₂C(CH₃)3)*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)PtCl(CH(CH₃)CO₂C(CH₃)3)*CH₂Cl₂

There total 1 articles about ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)PtCl(CH(CH₃)CO₂C(CH₃)3)*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[PtCl(Me)(1,2-bis(diphenylphosphino)ethane)] + dichloromethane (75-09-2) + N2CHCO2C(CH3)3 (1086219-10-4) → ((C6H5)2PCH2CH2P(C6H5)2)PtCl(CH(CH3)CO2C(CH3)3)*CH2Cl2 (916769-16-9)

Guidance literature:

In dichloromethane; under N2; N2CHCO2-t-Bu added to stirring soln. of Pt complex in CH2Cl2; stirred at 20°C for 16 h; concd. under vac.; petroleum ether added; ppt. washed with petroleum ether; dried under vac.; recrystd. from CH2Cl2-petroleum ether; elem. anal.;

DOI:10.1021/om060631n

Reference yield:

((C6H5)2PCH2CH2P(C6H5)2)PtCl(CH(CH3)CO2C(CH3)3)*CH2Cl2 (916769-16-9) + dimethyl zinc(II) (544-97-8) → ((C6H5)2PCH2CH2P(C6H5)2)Pt(CH3)(CH(CH3)CO2C(CH3)3) (916769-17-0) + cis-PtMe2(1,2-bis(diphenylphosphino)ethane) (15630-18-9)

Guidance literature:

In toluene; under N2; ZnMe2 in toluene added to stirring slurry of Pt complex in toluene at 20°C; filtered through Celite; filtrate concd. under vac.; petroleum ether added; ppt. dried under vac.; detd. by (31)P NMR spectra; mixt. of initial and two resultant Pt complexes obtained;

DOI:10.1021/om060631n

upstream raw materials:

dichloromethane

N₂CHCO₂C(CH₃)3

Downstream raw materials:

((C₆H₅)2PCH₂CH₂P(C₆H₅)2)Pt(CH₃)(CH(CH₃)CO₂C(CH₃)3)

cis-PtMe2(1,2-bis(diphenylphosphino)ethane)