cis-3-methoxycyclohexanol

Base Information

• Chemical Name: cis-3-methoxycyclohexanol
• CAS No.: 16327-00-7
• Molecular Formula: C₇H₁₄O₂
• Molecular Weight: 130.187
• Mol file: 16327-00-7.mol

Synonyms:

Chemical Property of cis-3-methoxycyclohexanol

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cis-3-methoxycyclohexanol

There total 20 articles about cis-3-methoxycyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

O-methylresorcine (150-19-6) → 3-methoxycyclohexan-1-ol (16327-00-7,89794-53-6)

Guidance literature:

With nickel(II) oxide; hydrogen; palladium; In hexane; at 80 ℃; for 10h; under 15001.5 Torr;

DOI:10.1039/c3ra45600e

Reference yield: 92.0%

1-methoxy-3-phenoxybenzene (1655-68-1) → 3-methoxycyclohexan-1-ol (16327-00-7,89794-53-6) + cyclohexane (110-82-7,25012-93-5)

Guidance literature:

With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine; In toluene; at 70 ℃; for 5h; Micellar solution;

DOI:10.1039/c2cc34454h

Reference yield: 88.0%

3,3’-oxybis(methoxybenzene) (82994-21-6) → 2-methoxycyclohexane (931-56-6) + 3-methoxycyclohexan-1-ol (16327-00-7,89794-53-6)

Guidance literature:

With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine; In toluene; at 70 ℃; for 5h; Micellar solution;

DOI:10.1039/c2cc34454h

upstream raw materials:

cyclohexane-1,3-diol

methyl iodide

1-methoxy-3-phenoxybenzene

3,3’-oxybis(methoxybenzene)

Downstream raw materials:

trans-1,3-dimethoxycyclohexane

cis-1,3-dimethoxycyclohexane

cis-1,3-cyclohexanediol

trans-1,3-cyclohexanediol

Refernces

• 1、 Ramaraj, Ayyappan,Nethaji, Munirathinam,Jagirdar, Balaji R.. "Hydrogenation of CO2, carbonyl and imine substrates catalyzed by [IrH3(PhPNHP)] complex". supporting information. p. 25 - 34. Retrieved 2019/01/24.
• 2、 Shi, Juanjuan,Zhao, Mengsi,Wang, Yingyu,Fu, Jie,Lu, Xiuyang,Hou, Zhaoyin. "Upgrading of aromatic compounds in bio-oil over ultrathin graphene encapsulated Ru nanoparticles". supporting information. p. 5842 - 5848. Retrieved 2016/05/24.