Cyclohexyl methyl ether

Base Information

• Chemical Name: Cyclohexyl methyl ether
• CAS No.: 931-56-6
• Molecular Formula: C7H14O
• Molecular Weight: 114.188
• Hs Code.: 2909209000
• European Community (EC) Number: 805-874-4
• UNII: I340UAT8HB
• DSSTox Substance ID: DTXSID10239268
• Nikkaji Number: J99.906G
• Wikidata: Q27280300
• Mol file: 931-56-6.mol

Synonyms:Cyclohexyl methyl ether;METHOXYCYCLOHEXANE;931-56-6;1-Methoxycyclohexane;Cyclohexane, methoxy-;Ether, cyclohexyl methyl;methoxy-cyclohexane;Methyl cyclohexyl ether;UNII-I340UAT8HB;I340UAT8HB;cyclohexylmethyl ether;CyOMe;ANISOLE, HEXAHYDRO-;SCHEMBL40788;(+/-)-2-methoxycyclohexane;SCHEMBL4648218;SCHEMBL12891667;DTXSID10239268;MFCD00154087;AKOS006275744;FT-0659790;M2374;D91594;A844461;Q27280300;1,3-DIMETHYL-4-NITRO-1H-PYRAZOLE-5-CARBOXYLICACIDETHYLESTER

Chemical Property of Cyclohexyl methyl ether

Chemical Property:

• Melting Point: -74°C(lit.)
• Refractive Index: 1.4330-1.4370
• Boiling Point: 133 °C at 760 mmHg
• Flash Point: 20.7 °C
• PSA: 9.23000
• Density: 0.86g/cm³
• LogP: 1.96550
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 114.104465066
• Heavy Atom Count: 8
• Complexity: 55.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methoxycyclohexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1CCCCC1

Technology Process of Cyclohexyl methyl ether

There total 145 articles about Cyclohexyl methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + methyl iodide (74-88-4) → 2-methoxycyclohexane (931-56-6) + 2-Methylcyclohexanone (583-60-8)

Guidance literature:

With 18-crown-6 ether; potassium; Product distribution; Mechanism; other ketones; other alkylating agents;

DOI:10.1016/S0040-4020(01)81523-4

Reference yield: 17.0%

2-methoxy-phenol (90-05-1) → methanol (67-56-1) + p-cresol (106-44-5) + 2-methoxycyclohexane (931-56-6) + cyclohexane (110-82-7,25012-93-5) + 1,2-Cyclohexanediol (931-17-9) + 2-methoxycyclohexanol (2979-24-0) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + 3-methyl-phenol (108-39-4) + ortho-cresol (95-48-7,77504-84-8) + cyclohexanol (108-93-0) + phenol (108-95-2,27073-41-2)

Guidance literature:

With hydrogen; ruthenium; at 150 - 300 ℃; for 4h; Product distribution / selectivity;

Reference yield: 2.6%

methanol (67-56-1) + Cyclohexanecarboxylic acid (98-89-5) → methyl cyclohexylcarboxylate (4630-82-4) + 2-methoxycyclohexane (931-56-6) + cyclohexylcyclohexane (92-51-3) + cyclohexane (110-82-7,25012-93-5) + cyclohexene (110-83-8) + cyclohexanol (108-93-0)

Guidance literature:

With tetra-n-butylammonium salt; at 0 ℃; for 5h; Product distribution; Mechanism; Irradiation; platinum electrode, 200 mA/cm², var. cell potential, presence of ultrasound;

DOI:10.1039/c39890000603

upstream raw materials:

1-methoxy-cyclohex-1-ene

cyclohexyl chloride

sodium methylate

semicarbazide hydrochloride

Downstream raw materials:

cyclohexene

methanol

cyclohexane

cyclohexyl chloride

Refernces

• 1、 Attina, Marina,Cacace, Fulvio,Marzio, Annito di. "Evaluation of the Arrhenius Parameters for the Thermal Isomerization of a Gaseous Ion. The Temperature Dependence of the Cyclohexylium Ion Unimolecular Rearrangement". . p. 6004 - 6008. Retrieved 1989.
• 2、 Antil, Neha,Kumar, Ajay,Akhtar, Naved,Begum, Wahida,Chauhan, Manav,Newar, Rajashree,Rawat, Manhar Singh,Manna, Kuntal. "Chemoselective and Tandem Reduction of Arenes Using a Metal–Organic Framework-Supported Single-Site Cobalt Catalyst". supporting information. p. 1031 - 1040. Retrieved 2022/01/19.
• 3、 Kalinina,Kulikov,Cherednichenko,Maximov,Karakhanov. "The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components". . p. 1061 - 1070. Retrieved 2021/09/06.