((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃

Base Information

Chemical Name:((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃
CAS No.:219598-56-8
Molecular Formula:C₂₇H₃₃F₃MoN₆Si
Molecular Weight:622.62
Hs Code.:

((4-FC<sub>6</sub>H<sub>4</sub>NCH<sub>2</sub>CH<sub>2</sub>)3N)Mo-N=N-SiMe<sub>3</sub>

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Chemical Property of ((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃

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Technology Process of ((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃

There total 1 articles about ((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 75-77-4
chloro-trimethyl-silane

: 219598-53-5
(2,2',2''-tris(4-fluorophenylphenylamino)triethylamine)MoCl

: 7727-37-9
nitrogen

: 219598-56-8
((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃

Guidance literature:: With sodium naphthalenide; In tetrahydrofuran; under N2 atm. to soln. sodium naphthalenide in THF at -40°C was added soln. (ArN3N)MoCl in THF, react. mixt. was allowed to warm to room temp. for 30 min, cooled to -40°C, soln. Me3SiCl in THF was addedand allowed to warm to room temp.; THF was removed in vacuo, residue was extd. with Et2O, filtered, and concd. in vacuo, residue was washed with pentane and dried in vacuo; elem. anal.;
DOI:10.1021/ic001123n

Reference yield: 99.0%

: 219598-56-8
((4-FC₆H₄NCH₂CH₂)3N)Mo-N=N-SiMe₃

: 108-88-3,15644-74-3,16713-13-6
toluene

: 333-27-7
methyl trifluoromethanesulfonate

: (((4-FC₆H₄NCH₂CH₂)3N)Mo=N-N(Me)(SiMe₃))OTf(toluene)0.5

Guidance literature:: In toluene; under N2 atm. soln. methyl triflate in toluene was added at -35°Cto soln. ((ArNCH2CH2)3N)MoNNSiMe3 in toluene and stirred for 1 h; ppt was collected, washed with toluene and pentane, and dried in vacuo; elem. anal.;
DOI:10.1021/ic001123n