(2R)-2-methylhexanal

Base Information

Chemical Name:(2R)-2-methylhexanal
CAS No.:132151-88-3
Molecular Formula:C7H14O
Molecular Weight:114.188
Hs Code.:
UNII:LKS72L33JG
Nikkaji Number:J876.964H

Synonyms:(2R)-2-methylhexanal;(-)-2-Methylhexanal;2-Methylhexanal, (R)-;2-Methylhexanal, (-)-;LKS72L33JG;Hexanal, 2-methyl-, (2R)-;(R)-alpha-Methylhexanal;UNII-LKS72L33JG;132151-88-3;(R)-2-Methylhexanal;(R)-2-methyl-1-hexanal;SCHEMBL3484833;BHVGMUDWABJNRC-SSDOTTSWSA-N;(R)-.ALPHA.-METHYLHEXANAL;EN300-7281435

Suppliers and Price of (2R)-2-methylhexanal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (2R)-2-methylhexanal

Chemical Property:

XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:114.104465066
Heavy Atom Count:8
Complexity:59.4

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCC(C)C=O
Isomeric SMILES:CCCC[C@@H](C)C=O

Technology Process of (2R)-2-methylhexanal

There total 1 articles about (2R)-2-methylhexanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 592-41-6,25067-06-5
1-hexene

: 201230-82-2
carbon monoxide

: 111-71-7
heptanal

: 132151-88-3
R-(-)-2-methylhexanal

: 66875-71-6
S-(+)-2-methylhexanal

Guidance literature:: With acetylacetonatodicarbonylrhodium(l); hydrogen; (R,S)-binaphos; In benzene; under 76000 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja970049d

Reference yield:

: 132151-88-3
R-(-)-2-methylhexanal

: 153108-88-4
(7S,8R,8aS)-8-(benzyloxy)-7-hydroxy-8-methyl-6-(E)-<(2R)-2-methylpentylidene>octahydroindolizidine

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Ph₃P / 1.) CH₂Cl₂, -10 deg C, 20 min, 2.) CH₂Cl₂, a) -78 deg C, 10 min, b) -20 deg C, 30 min

2: 1.) n-BuLi / 1.) THF, -78 deg C, 2 h, 2.) THF, a) -78 deg C, 2 h, b) -50 deg C, 8 h

3: 90 percent / AgNO₃ / ethanol / 20 h / Ambient temperature

4: 88 percent / NaI, aq. CH₂O, camphorsulfonic acid monohydrate / 1 h / 100 °C

5: 1.) s-BuLi, 2.) MeOH / 1.) THF, cyclohexane, -78 deg C, 1.75 h, 2.) THF, hexane, -78 deg C

With methanol; n-butyllithium; formaldehyd; camphor-10-sulfonic acid; sec.-butyllithium; silver nitrate; triphenylphosphine; sodium iodide; In ethanol;
DOI:10.1021/ja961640y

Reference yield:

: 132151-88-3
R-(-)-2-methylhexanal

: 182001-21-4
(3R,4R,4aS)-4-Benzyloxy-4-methyl-3-((R)-3-methyl-hept-1-ynyl)-hexahydro-pyrrolo[1,2-c][1,3]oxazine

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Ph₃P / 1.) CH₂Cl₂, -10 deg C, 20 min, 2.) CH₂Cl₂, a) -78 deg C, 10 min, b) -20 deg C, 30 min

2: 1.) n-BuLi / 1.) THF, -78 deg C, 2 h, 2.) THF, a) -78 deg C, 2 h, b) -50 deg C, 8 h

3: 90 percent / AgNO₃ / ethanol / 20 h / Ambient temperature

With n-butyllithium; silver nitrate; triphenylphosphine; In ethanol;
DOI:10.1021/ja961640y