trans-[Pd(C₆F₅)(AsCyPh₂)2Br]

Base Information

• Chemical Name: trans-[Pd(C₆F₅)(AsCyPh₂)2Br]
• CAS No.: 1042933-44-7
• Molecular Formula: C₄₂H₄₂As₂BrF₅Pd
• Molecular Weight: 977.955
• Mol file: 1042933-44-7.mol

Synonyms:

Chemical Property of trans-[Pd(C₆F₅)(AsCyPh₂)2Br]

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of trans-[Pd(C₆F₅)(AsCyPh₂)2Br]

There total 1 articles about trans-[Pd(C₆F₅)(AsCyPh₂)2Br] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

bis(acetonitrile)bromo(pentafluorophenyl)palladium(II) (125475-73-2) + cyclohexyl-diphenyl-arsine (38563-50-7) → trans-[Pd(C6F5)(AsCyPh2)2Br] (1042933-44-7)

Guidance literature:

In diethyl ether; (N2) the complex was added to As(C6H5)2(C6H11) in diethyl ether, the soln. was stirred for 45 min; the solvent was removed, hexane was added, cooled to -18°C, filtered, vac.-dried; elem. anal.;

DOI:10.1021/om800264a

Reference yield: 68.0%

silver tetrafluoroborate (14104-20-2) + trans-[Pd(C6F5)(AsCyPh2)2Br] (1042933-44-7) → trans-[Pd(C6F5)(AsPh2Cy)2(NCMe)]BF4 (1042933-59-4)

Guidance literature:

In acetonitrile; (N2) to a soln. of AgBF4 in CH3CN was added Pd-complex, the soln. was stirred for 2 h; filtered, evapd. to dryness, stirred vigorously with diethyl ether, ppt.was filtered and vac.-dried; elem. anal.;

DOI:10.1021/om800264a

upstream raw materials:

bis(acetonitrile)bromo(pentafluorophenyl)palladium(II)

cyclohexyl-diphenyl-arsine

Downstream raw materials:

trans-[Pd(C₆F₅)(AsPh₂Cy)2(NCMe)]BF₄