(C₆H₅)3GeCH₂SCH₃

Base Information

• Chemical Name: (C₆H₅)3GeCH₂SCH₃
• CAS No.: 179676-26-7
• Molecular Formula: C₂₀H₂₀GeS
• Molecular Weight: 365.035
• Mol file: 179676-26-7.mol

Synonyms:

Chemical Property of (C₆H₅)3GeCH₂SCH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)3GeCH₂SCH₃

There total 1 articles about (C₆H₅)3GeCH₂SCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

chloro-methylsulfanyl-methane (2373-51-5) + triphenylgermanium bromide (3005-32-1) → (C6H5)3GeCH2SCH3 (179676-26-7)

Guidance literature:

With Mg; In tetrahydrofuran; treatment of MeSCH2Cl with Mg, slow addn. of Ge-compd. (stirring), standing overnight; addn. of aq. NH4OH, drying org. layer (MgSO4), evapn. (reduced pressure), crystn. (EtOH); elem. anal.;

DOI:10.1016/0022-328X(96)06140-2

Reference yield: 75.0%

(C6H5)3GeCH2SCH3 (179676-26-7) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → (C6H5)3GeCH2S(O)CH3 (179676-28-9)

Guidance literature:

In chloroform; equimolar amts., room temp., 3 h; washing (aq. NaHCO3), drying (MgSO4), evapn. (reduced pressure), crystn.(EtOH); elem. anal.;

DOI:10.1016/0022-328X(96)06140-2

Reference yield:

(C6H5)3GeCH2SCH3 (179676-26-7) → (C6H5)3GeCH2S(O)2CH3 (179676-31-4)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform

2: chloroform

In chloroform;

DOI:10.1016/0022-328X(96)06140-2

upstream raw materials:

chloro-methylsulfanyl-methane

triphenylgermanium bromide

Downstream raw materials:

(C₆H₅)3GeCH₂S(O)CH₃

(C₆H₅)3GeCH₂S(O)2CH₃