C₅H₅Ni(P(C₄H₉-n)3)SC(S)NHC₆H₁₁-cyclo

Base Information

• Chemical Name: C₅H₅Ni(P(C₄H₉-n)3)SC(S)NHC₆H₁₁-cyclo
• CAS No.: 52201-70-4
• Molecular Formula: C₅H₅*C₇H₁₂NS₂*C₁₂H₂₇P*Ni
• Molecular Weight: 500.416
• Mol file: 52201-70-4.mol

Synonyms:

Chemical Property of C₅H₅Ni(P(C₄H₉-n)3)SC(S)NHC₆H₁₁-cyclo

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅H₅Ni(P(C₄H₉-n)3)SC(S)NHC₆H₁₁-cyclo

There total 2 articles about C₅H₅Ni(P(C₄H₉-n)3)SC(S)NHC₆H₁₁-cyclo which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

C5H5Ni(P(C4H9-n)3)SH + isothiocyanatocyclohexane (1122-82-3) → C5H5Ni(P(C4H9-n)3)SC(S)NHC6H11-cyclo (52201-70-4)

Guidance literature:

In hexane; with 10-fold excess of (C6H11-cyclo)NCS, at room temp., several h; sepn. of the crystals, or first purifn. with chromy. on SiO2; crystn. from benzene/n-hexane or ether/n-hexane;

DOI:10.1016/S0022-328X(00)93694-5

Reference yield: 71.0%

{C5H5Ni(P(C4H9-n)3)2}Cl + monocyclohexyldithiocarbamate sodium (2801-07-2) → C5H5Ni(P(C4H9-n)3)SC(S)NHC6H11-cyclo (52201-70-4)

Guidance literature:

In water; room temp.; with excess of NaSC(S)NHC6H11; extn. of the brown ppt. with ether or benzene; drying, evapn. in vac.; recrystn. from benzene or benzene/hexane;

DOI:10.1016/S0022-328X(00)93694-5

upstream raw materials:

monocyclohexyldithiocarbamate sodium

isothiocyanatocyclohexane