{(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)}

Base Information

• Chemical Name: {(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)}
• CAS No.: 83614-07-7
• Molecular Formula: C₄₃H₅₁FeN₄O
• Molecular Weight: 695.751
• Mol file: 83614-07-7.mol

Synonyms:

Chemical Property of {(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)}

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of {(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)}

There total 1 articles about {(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

{(octaethylporphyrin)FeClO4}(1+) (50540-30-2) + 4-methoxyphenyl magnesium bromide (13139-86-1) → {(C20H4(C2H5)8N4)Fe(C6H4OCH3)} (83614-07-7)

Guidance literature:

In diethyl ether; benzene; complex stirred in C6H6, org. educt soln. in ether added, stirred for 1h at room temp.; concd. (vac.), chromd. (SiO2, C6H6), evapd. (vac.), recrystd. (C6H6/petroleum ether); elem. anal.;

DOI:10.1016/S0022-328X(00)85854-4

Reference yield: 80.0%

{(C20H4(C2H5)8N4)Fe(C6H4OCH3)} (83614-07-7) + nitrogen(II) oxide (10102-43-9) → octaethylporphyrin iron(II) nitrosyl (55917-58-3) + {(C20H4(C2H5)8N4)Fe(C6H4OCH3)(NO)} (89672-73-1)

Guidance literature:

reaction of a solid complex in NO atm. or a soln. of complex in toluenesaturated with NO at -28°C;

DOI:10.1016/S0022-328X(00)98684-4

Reference yield:

{(C20H4(C2H5)8N4)Fe(C6H4OCH3)} (83614-07-7) + nitrogen(II) oxide (10102-43-9) → {(C20H4(C2H5)8N4)Fe(C6H4OCH3)(NO)} (89672-73-1)

Guidance literature:

In neat (no solvent); exposure of degassed solid ((C20H4(C2H5)8N4)Fe(C6H4OCH3)) to 1 atm of nitric oxide;; elem. anal.;;

upstream raw materials:

{(octaethylporphyrin)FeClO₄}⁽¹⁺⁾

4-methoxyphenyl magnesium bromide

Downstream raw materials:

octaethylporphyrin iron(II) nitrosyl

{(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)(NO)}

Refernces