cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4

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Chemical Name:cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4
CAS No.:1316861-00-3
Molecular Formula:C₃₂H₁₂BF₂₄*C₄₇H₄₄IrOP₂
Molecular Weight:1742.25
Hs Code.:

Synonyms:

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Chemical Property of cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4

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Technology Process of cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4

There total 1 articles about cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 1316861-00-3
cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4

Guidance literature:: In dichloromethane; Schlenk or glove-box techniques used under Ar, soln. of Xantphos (0.29 mmol) in CH2Cl2 dropwise added to CH2Cl2 suspn. of (Ir(cod)Cl)2 (0.15 mmol) and Na(B(C6H3(CF3)2)4) (0.29 mmol), stirred at ambient temp. for 2 h; filtered, solvent removed under vac., recrystd. from CH2Cl2/pentane at room temp.; elem. anal., XRD;
DOI:10.1016/j.jorganchem.2011.01.036

Reference yield: 52.2%

: 1316861-00-3
cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4

: 1333-74-0
hydrogen

: fac-[Ir(κ3-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(H)(μ-H)]2(B(C6H3(CF3)2)4)2

Guidance literature:: In fluorobenzene; High Pressure; Schlenk or glove-box techniques used under Ar, C6H5F soln. of (Ir(Xantphos)(COD))B(C6H3(CF3)2)4 (0.045 mmol) placed under H2 (4 atm) at ambient temp. for approx. 48 h; pptd. out of soln.; elem. anal., XRD;
DOI:10.1016/j.jorganchem.2011.01.036

Reference yield:

: 1316861-00-3
cis-[Ir(κ2-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(1,5-cyclooctadiene)]B(C6H3(CF3)2)4

: 1333-74-0
hydrogen

: 1316861-02-5
[Ir(κ3-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(σ,eta.2-C8H13)]B(C6H3(CF3)2)4

Guidance literature:: In [⁽²⁾H₆]acetone; High Pressure; Schlenk or glove-box techniques used under Ar, acetone-d6 soln. of (Ir(Xantphos)(COD))B(C6H3(CF3)2)4 (5.74E-3 mmol) placed under H2 (approx. 4 atm) for 10 min; not isolated; detected spect.;
DOI:10.1016/j.jorganchem.2011.01.036