allyl oleate

Base Information

• Chemical Name: allyl oleate
• CAS No.: 45274-31-5
• Molecular Formula: C₂₁H₃₈O₂
• Molecular Weight: 322.532
• Mol file: 45274-31-5.mol

Synonyms:

Chemical Property of allyl oleate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl oleate

There total 3 articles about allyl oleate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.3%

cis-Octadecenoic acid (112-80-1,2027-47-6) + 3-chloroprop-1-ene (107-05-1) → allyl oleate (45274-31-5,100740-04-3,19855-52-8)

Guidance literature:

With N,N,N',N'-tetramethylguanidine; In N,N-dimethyl-formamide; at 70 ℃; for 12h;

Reference yield: 80.0%

cis-Octadecenoic acid (112-80-1,2027-47-6) + allyl alcohol (107-18-6) → allyl oleate (45274-31-5,100740-04-3,19855-52-8)

Guidance literature:

With toluene-4-sulfonic acid; for 8h; Reflux;

DOI:10.1002/pola.24671

Reference yield: 79.0%

potassium oleate (143-18-0) + allyl bromide (106-95-6) → allyl oleate (45274-31-5,100740-04-3,19855-52-8)

Guidance literature:

tetrabutylammomium bromide; In dichloromethane; at 20 - 22 ℃; for 40h;

DOI:10.1007/BF00817604

upstream raw materials:

cis-Octadecenoic acid

allyl alcohol

potassium oleate

allyl bromide

Downstream raw materials:

cis-Octadecenoic acid

Refernces

• 1、 Takagi, Koji,Fukuda, Hayato,Shuto, Satoshi,Otaka, Akira,Arisawa, Mitsuhiro. "Safe Removal of the Allyl Protecting Groups of Allyl Esters using a Recyclable, Low-Leaching and Ligand-Free Palladium Nanoparticle Catalyst". supporting information. p. 2119 - 2124. Retrieved 2015/06/23.
• 2、 Klan, Petr,Benovsky, Petr. "Phase-Transfer Catalyzed Synthesis of 2-Propenyl Esters of Carboxylic Acids". . p. 469 - 472. Retrieved 2007/10/02.