Furan, 5-methyl-2,2'-methylenedi-

Base Information

• Chemical Name: Furan, 5-methyl-2,2'-methylenedi-
• CAS No.: 13678-51-8
• Molecular Formula: C10H10O2
• Molecular Weight: 162.18500
• European Community (EC) Number: 603-976-1
• DSSTox Substance ID: DTXSID50344264
• Nikkaji Number: J101.436F
• Wikidata: Q82115989
• Mol file: 13678-51-8.mol

Synonyms:2-Furfuryl-5-methylfuran;2-(furan-2-ylmethyl)-5-methylfuran;Furan, 5-methyl-2,2'-methylenedi-;13678-51-8;Furan, 2-(2-furanylmethyl)-5-methyl-;5-methyl-2-furfurylfuran;SCHEMBL2266485;DTXSID50344264;2-(2-Furylmethyl)-5-methylfuran;2-(2-Furanylmethyl)-5-methylfuran;(5-Methyl-2-furyl)-2-furyl-methan;F87818

Chemical Property of Furan, 5-methyl-2,2'-methylenedi-

Chemical Property:

• Vapor Pressure: 0.244mmHg at 25°C
• Melting Point: 88-91 °C
• Boiling Point: 213.1±30.0 °C(Predicted)
• PSA: 26.28000
• Density: 1.076±0.06 g/cm3(Predicted)
• LogP: 2.77180
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 162.068079557
• Heavy Atom Count: 12
• Complexity: 147

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(O1)CC2=CC=CO2

Technology Process of Furan, 5-methyl-2,2'-methylenedi-

There total 9 articles about Furan, 5-methyl-2,2'-methylenedi- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

2-methylfuran (534-22-5) + (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) → furan 2-(2-furanylmethyl)-5-methyl (13678-51-8)

Guidance literature:

With 1-methyl-3-(4-sulfobutyl)-1H-imidazol-3-ium hydrogensulfate; In water; at 65 ℃; for 2h; Green chemistry;

DOI:10.1039/c7gc01654a

Reference yield: 38.0%

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + 5-methylfuran-2-carboxylic acid (1917-15-3) → furan 2-(2-furanylmethyl)-5-methyl (13678-51-8)

Guidance literature:

With water; In cyclohexane; at 100 ℃; for 2h; Schlenk technique;

DOI:10.1039/c9gc03179k

Reference yield: 20.0%

furfural (98-01-1) + isopropyl alcohol (67-63-0,8013-70-5) → 2-methylfuran (534-22-5) + acetone (67-64-1) + furan 2-(2-furanylmethyl)-5-methyl (13678-51-8)

Guidance literature:

With 5 wt% ruthenium/carbon; at 180 ℃; for 5h; Sealed tube; Inert atmosphere;

DOI:10.1016/j.apcata.2014.04.018

upstream raw materials:

furfural

isopropyl alcohol

(+/-)-2-pentanol

ethanol