Allyl 4-nitrobenzenesulfenate

Base Information

• Chemical Name: Allyl 4-nitrobenzenesulfenate
• CAS No.: 28525-01-1
• Molecular Formula: C₉H₉NO₃S
• Molecular Weight: 211.241
• Mol file: 28525-01-1.mol

Synonyms:

Chemical Property of Allyl 4-nitrobenzenesulfenate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Allyl 4-nitrobenzenesulfenate

There total 2 articles about Allyl 4-nitrobenzenesulfenate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrobenzenesulfenyl chloride (937-32-6) + Lithium allyl alcoholate (52203-12-0) → Allyl 4-nitrobenzenesulfenate (28525-01-1)

Guidance literature:

In Dimethyl ether; trichlorofluoromethane;

DOI:10.1021/ja00710a051

Reference yield:

4-nitrobenzenesulfenyl chloride (937-32-6) + allyl alcohol (107-18-6) → Allyl 4-nitrobenzenesulfenate (28525-01-1) + Allyl 4-nitrobenzenesulfinate (161941-54-4)

Guidance literature:

With triethylamine; In dichloromethane; 1.) dry ice/acetone bath temp., 15 min, 2.) dry ice/acetone bath temp., to r.t., 30 min;

DOI:10.1021/jo00102a057

Reference yield:

Allyl 4-nitrobenzenesulfenate (28525-01-1) → 3-(p-nitrophenylsulfinyl)prop-1-ene (81650-42-2,128326-65-8,128326-66-9)

Guidance literature:

With (Rearrangement); In benzene; at 6.8 - 20 ℃; Kinetics;

DOI:10.1021/ja00710a051

upstream raw materials:

4-nitrobenzenesulfenyl chloride

allyl alcohol

Lithium allyl alcoholate

Downstream raw materials:

Allyl 4-nitrobenzenesulfinate

3-(p-nitrophenylsulfinyl)prop-1-ene

Allyl 4-nitrophenyl sulfone