[Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF₆]

Base Information

• Chemical Name: [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF₆]
• CAS No.: 876661-22-2
• Molecular Formula: C₃₃H₂₃N₁₀Ru*F₆P
• Molecular Weight: 805.647
• Mol file: 876661-22-2.mol

Synonyms:

Chemical Property of [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF₆]

There total 1 articles about [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ammonium hexafluorophosphate + silver(I) hexafluorophosphate (26042-63-7) + 5-(4-cyanophenyl)tetrazole (14389-10-7) + 2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate (83572-47-8) + acetone (67-64-1) → [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF6] (876661-22-2) + [(Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl))2(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF6]3

Guidance literature:

With (C₂H₅)3N; In acetone; byproducts: AgCl; Ru complex dissolved in acetone in a flask protected from light, AgPF6 added, refluxed for 4 h, filtered, added dropwise to a soln. of ligand/(C2H5)3N, refluxed overnight; cooled to room temp., concd., added to an aq. soln. of NH4PF6, extd. (CH2Cl2), the org. layers dried (MgSO4), evapd. (vac.), dissolved in acetone, added to Et2O, filtered, chromd. (alumina, acetone/toluene to acetone), evapd.;

DOI:10.1021/ic0514905

Reference yield: 90.0%

[Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF6] (876661-22-2) + trifluorormethanesulfonic acid (1493-13-6) → [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(H)TBN)][CF3SO3]2

Guidance literature:

In dichloromethane; a soln. of Ru complex cooled to -50°C, HO3SCF3 in CH2Cl2 added dropwise, reacted for 30 min, allowed to warm to room temp. and stirred for 6 h; evapd., dissolved in MeCN, added to Et2O, filtered (Ar);

DOI:10.1021/ic0514905

Reference yield: 78.0%

ammonium hexafluorophosphate + [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(1H-tetrazol-5-yl)benzonitrile(-1H))][PF6] (876661-22-2) + methyl trifluoromethanesulfonate (333-27-7) → [Ru(2,2':6',2''-terpyridine)(2,2'-bipyridyl)(4-(Me)TBN)][PF6]2

Guidance literature:

In dichloromethane; a soln. of Ru complex cooled to -50°C, CH3O3SCF3 in CH2Cl2 added dropwise, reacted for 30 min, allowed to warm to room temp. and stirred for 6 h; evapd., dissolved in MeCN, added to an aq. soln. contg. NH4PF6, extd. (CH2Cl2), the org. layers dried (MgSO4), evapd. (vac.);

DOI:10.1021/ic0514905

upstream raw materials:

silver(I) hexafluorophosphate

5-(4-cyanophenyl)tetrazole

2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate

acetone