Ethenesulfonic acid, phenyl-, phenyl ester

Base Information

• Chemical Name: Ethenesulfonic acid, phenyl-, phenyl ester
• CAS No.: 13719-31-8
• Molecular Formula: C14H12O3S
• Molecular Weight: 260.313
• Mol file: 13719-31-8.mol

Synonyms:

Chemical Property of Ethenesulfonic acid, phenyl-, phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethenesulfonic acid, phenyl-, phenyl ester

There total 8 articles about Ethenesulfonic acid, phenyl-, phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

tert-butyldimethyl(phenoxy)silane (18052-27-2) + (Z)-2-phenylethene-1-sulfonyl fluoride → 2-Phenylvinylsulfonsaeure-phenylester (13719-31-8,17299-26-2)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 50 ℃; for 0.5h;

DOI:10.1002/ejoc.201900799

Reference yield: 88.0%

β-styrenesulfonyl chloride (4091-26-3) + phenol (108-95-2,27073-41-2) → phenyl β-styrenesulfonate (13719-31-8)

Guidance literature:

triethylamine; In 1,4-dioxane; for 0.25h;

Reference yield: 86.0%

trans 2-phenylethenesulfonyl chloride (52147-97-4) + phenol (108-95-2,27073-41-2) → 2-Phenylvinylsulfonsaeure-phenylester (13719-31-8,17299-26-2)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 5h;

DOI:10.1021/acsmedchemlett.9b00163

upstream raw materials:

β-styrenesulfonyl chloride

phenol

(E)-2-Phenyl-ethenesulfonic acid 4-benzyloxy-phenyl ester

trans 2-phenylethenesulfonyl chloride

Downstream raw materials:

3-nitro-2-phenylpropane-1-sulfonic acid phenyl ester

2-phenylethane-1,2-dibromo-1-phenylsulfonate ester

1-phenyl-1-p-tolyl-ethylene

C₂₁H₂₀O₃S

Refernces

• 1、 Choi, Ji Won,Shin, Su Jeong,Kim, Hyeon Ji,Park, Jong-Hyun,Kim, Hyeon Jeong,Lee, Elijah Hwejin,Pae, Ae Nim,Bahn, Yong Sun,Park, Ki Duk. "Antioxidant, Anti-inflammatory, and Neuroprotective Effects of Novel Vinyl Sulfonate Compounds as Nrf2 Activator". . p. 1061 - 1067. Retrieved 2019.
• 2、 Vizgert, R. V.,Enya, V. I.,Tuchapskii, I. M.,Pekhtereva, T. M.. "KINETICS AND FEATURES OF THE HYDROLYSIS OF ARYL 2-PHENYLETHENESULFONATES". . p. 2318 - 2322. Retrieved 2007/10/02.