dichloro bis(benzylamine) palladium (II)

Base Information

• Chemical Name: dichloro bis(benzylamine) palladium (II)
• CAS No.: 19046-92-5
• Molecular Formula: C₁₄H₁₈Cl₂N₂Pd
• Molecular Weight: 391.636
• Mol file: 19046-92-5.mol

Synonyms:

Chemical Property of dichloro bis(benzylamine) palladium (II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro bis(benzylamine) palladium (II)

There total 4 articles about dichloro bis(benzylamine) palladium (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

palladium (7440-05-3) + benzonitrile (100-47-0) → trans-Cl2Pd(H2NCH2C6H5)2 (19046-92-5,55176-74-4)

Guidance literature:

With HCl; In ethanol; Electrochem. Process; electrolysis of Pd-foil, HCl, EtOH and benzonitrile at 25 V for 60 min;; evapn. of solvent over a steam bath, cooling to room temp., elem. anal.;

DOI:10.1016/S0277-5387(00)83662-1

Reference yield:

[Pd(OAc)2(PhCH2NH2)2] (187852-72-8,93916-90-6) + sodium chloride (7647-14-5) → trans-Cl2Pd(H2NCH2C6H5)2 (19046-92-5,55176-74-4)

Guidance literature:

In water; acetone; for 12h;

DOI:10.1016/j.ica.2017.02.027

Reference yield:

tetrachloropalladium anion (14349-67-8) + benzylamine (100-46-9) → dichloro bis(benzylamine) palladium (II) (19046-92-5,55176-74-4)

Guidance literature:

In water; on react. of benzyl amine with neutral aq. soln. of (PdCl4)(2-), first forming of a weakly reddish ppt. (Vauquelin's salt), which is dissolved in excess benzyl amine (colorless); pptn. on addn. of HCl; washing with cold H2O;;

upstream raw materials:

palladium

benzonitrile

benzylamine

[Pd(OAc)₂(PhCH₂NH₂)₂]

Downstream raw materials:

diamminedichloropalladium(II)

Refernces