(tris(2-diphenylphosphinoethyl)phosphine)RhSH

Base Information

Chemical Name:(tris(2-diphenylphosphinoethyl)phosphine)RhSH
CAS No.:116363-50-9
Molecular Formula:C₄₂H₄₃P₄RhS
Molecular Weight:806.67
Hs Code.:

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Chemical Property of (tris(2-diphenylphosphinoethyl)phosphine)RhSH

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Technology Process of (tris(2-diphenylphosphinoethyl)phosphine)RhSH

There total 2 articles about (tris(2-diphenylphosphinoethyl)phosphine)RhSH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: sodiumsulfide nonahydrate

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

: 2923-28-6
silver trifluoromethanesulfonate

: 116363-50-9
(tris(2-diphenylphosphinoethyl)phosphine)RhSH

Guidance literature:: In tetrahydrofuran; ethanol; byproducts: AgCl; under N2; soln. of AgCF3SO3 added to soln. of Rh-compd., stirred at 40-45°C for 1h, filtered, addn. of soln. of ligand, light red soln., addn. of Na2S in EtOH; addn. of EtOH, concd. slow, filtered (closed system), washed (EtOH, petroleum ether), dried under N2; elem. anal.;

Reference yield:

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

: 2923-28-6
silver trifluoromethanesulfonate

: 116363-50-9
(tris(2-diphenylphosphinoethyl)phosphine)RhSH

Guidance literature:: With H₂S; In tetrahydrofuran; ethanol; byproducts: AgCl; under N2; soln. of AgCF3SO3 added to soln. of Rh-compd., stirred for 40-45°C for 1h, filtered, addn. of soln. of ligand, light red soln., addn. of H2S (prepd. from S8 and (NBu4)BH4 in EtOH);

Reference yield: 85.0%

: 116363-50-9
(tris(2-diphenylphosphinoethyl)phosphine)RhSH

: 1493-13-6
trifluorormethanesulfonic acid

: (tris(2-diphenylphosphinoethyl)phosphine)RhSH(CF₃SO₃)

Guidance literature:: In tetrahydrofuran; anhydrous THF,; isolated after addn. of benzene, characterization by IR and (1)H and (31)P NMR;
DOI:10.1016/S0022-328X(00)99821-8