Technology Process of [Ru(5,10,15,20-tetraphenylporphyrinato)(CO)(H2O)]
There total 4 articles about [Ru(5,10,15,20-tetraphenylporphyrinato)(CO)(H2O)] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
water; ethyl acetate;
(Ru(TPP)(CO)) was suspended in mixt. water and EtOAc (2:1) and refluxed and stirred for 4 h; react. mixt. was cooled, aq. layer was eliminated, org. layer was evapd.to dryness, residue was boiled in n-hexane, ppt. was filtered and dried in vacuo;
DOI:10.1021/ic048587w
- Guidance literature:
-
With
phenol;
In
water; N,N-dimethyl-formamide;
heating of mixt. of 5,10,15,20-tetraphenylporphyrine and Ru3(CO)12 in phenol for 1 h, cooling of melt, dissolving in DMF, pouring in water; pptn., filtration, washing with hot water, chromy. 2 times om alumina with CHCl3; elem. anal.;
DOI:10.1134/S0036023612030187
- Guidance literature:
-
In
further solvent(s);
mixt. of porphyrin and Ru3(CO)12 was refluxed in phenol for 1 h; melt cooled; dissolved in DMF; poured into water; ppt. filtered off; washed (hot water); residue was purified by chromy. on alumina (CHCl3 as eluent);
DOI:10.1134/S0036023610090147
