5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl

Base Information

• Chemical Name: 5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl
• CAS No.: 32073-84-0
• Molecular Formula: C45H28 N4 O Ru
• Molecular Weight: 741.814
• European Community (EC) Number: 620-639-4
• Mol file: 32073-84-0.mol

Synonyms:5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl;32073-84-0

Chemical Property of 5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl

Chemical Property:

• PSA: 49.84000
• LogP: 8.08520
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 4
• Exact Mass: 742.130652
• Heavy Atom Count: 51
• Complexity: 1240

Purity/Quality:

98%,99%, ^*data from raw suppliers

5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl Dye content ~80 % ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [C-]#[O+].[CH-]1C=C2C(=C3C=CC(=N3)C(=C4C=CC(=N4)[C-](C5=NC(=C(C1=N2)C6=CC=CC=C6)C=C5)C7=CC=CC=C7)C8=CC=CC=C8)C9=CC=CC=C9.[Ru+2]

Technology Process of 5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl

There total 8 articles about 5,10,15,20-Tetraphenyl-21H,23H-porphine ruthenium(II) carbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) (32073-84-0)

Guidance literature:

With propionic acid; at 140 ℃; for 0.5h; Microwave irradiation;

DOI:10.1002/ejic.201900428

Reference yield: 83.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) → (5,10,15,20-tetraphenylporphyrinato)(carbonyl)ruthenium(II) (32073-84-0)

Guidance literature:

In not given; according to D.P. Rillema, J.K. Nagle, L.F. Barringer, and T.J. Meyer, J. Am. Chem. Soc., 103 (1981) 56.;

DOI:10.1016/1381-1169(95)00067-4

Reference yield: 69.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) → carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) (32073-84-0)

Guidance literature:

In decalin; under N2 atm. Ru3(CO)3 and H2TPP were suspended in decalin and refluxed for 4 h; ppt. was filtered, washed withn-hexane and purified by flash chromy. on silica; elem. anal.;

DOI:10.1021/ic048587w

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

5,10,15,20-tetraphenyl-21H,23H-porphine

(meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II)

carbon monoxide

Downstream raw materials:

Ru(II)(TPP⁽¹⁺⁾)(CO)(Cl^(1-))

Ru(II)(5,10,15,20-tetraphenylporphyrinato)(CO)(pyridine)

{Ru(II)(tetraphenylporphyrin^(2-))(CO)(acetonitrile)}

ruthenium(II) (2-monofluoroethyl isocyanide)2 meso-tetraphenylporphyrine