[RuH(OAc-κ²O,O’)(triphos)]

Base Information

• Chemical Name: [RuH(OAc-κ²O,O’)(triphos)]
• CAS No.: 1003045-52-0
• Molecular Formula: C₄₃H₄₃O₂P₃Ru
• Molecular Weight: 785.804
• Mol file: 1003045-52-0.mol

Synonyms:

Chemical Property of [RuH(OAc-κ²O,O’)(triphos)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuH(OAc-κ²O,O’)(triphos)]

There total 2 articles about [RuH(OAc-κ²O,O’)(triphos)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

RuH(OAc)(PPh3)3 (311819-28-0,25087-75-6,55354-87-5) + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → [RuH(OAc-κ2O,O’)(triphos)] (1003045-52-0)

Guidance literature:

In toluene; byproducts: PPh3; (N2); std. Schlenk technique; suspn. of Ru complex and ligand in toluenewas refluxed for 30 min; cooled to room temp.; filtered; washed (toluene, Et2O); elem. anal.;

DOI:10.1021/ic701773a

Reference yield:

[RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)] (1003045-51-9) + hydrogen (1333-74-0) → [RuH(OAc-κ2O,O’)(triphos)] (1003045-52-0)

Guidance literature:

With Et₃N; In dichloromethane-d2; (Ar); std. Schlenk technique; soln. of Ru complex and Et3N (20 equiv.) in CD2Cl2 was heated at 50°C for 30 min under H2 (50 bar); NMR monitoring;

DOI:10.1021/ic701773a

Reference yield: 43.0%

methanesulfonic acid (75-75-2,98527-29-8) + [RuH(OAc-κ2O,O’)(triphos)] (1003045-52-0) → [Ru2(μ-CH3SO3)3(triphos)2]CH3SO3 + H[Ru(CH3SO3-κ1O)3(triphos)] + [Ru(CH3SO3-κ1O)(CH3SO3-κ2O,O’)(triphos)]

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201204270

upstream raw materials:

[RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)]

hydrogen

RuH(OAc)(PPh₃)3

[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

Downstream raw materials:

[RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)]