[Yb(TPP)(OAc)(MeOH)₂]

Base Information

• Chemical Name: [Yb(TPP)(OAc)(MeOH)₂]
• CAS No.: 1185986-66-6
• Molecular Formula: C₄₈H₃₉N₄O₄Yb
• Molecular Weight: 908.902
• Mol file: 1185986-66-6.mol

Synonyms:

Chemical Property of [Yb(TPP)(OAc)(MeOH)₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Yb(TPP)(OAc)(MeOH)₂]

There total 1 articles about [Yb(TPP)(OAc)(MeOH)₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methanol (67-56-1) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + ytterbium(III) acetate trihydrate → [ytterbium(III)(5,10,15,20-tetraphenylphorphirin-2H)(acetate)(methanol)2] (1185986-66-6)

Guidance literature:

In further solvent(s); to soln. of H2TPP in 1,2,4-trichlorobenzene added Yb(OAc)3 hydrate and mixt. heated under N2 to 210°C with stirring for 48 h; soln. cooled to 70°C and CH3OH added with stirring; solvent evapd. under vac.; ppt. redissolved in chloroform; chromy. on silica gel column (chloroform); compd. recrystd. from CH2Cl2/CH3OH; elem. anal.;

DOI:10.1016/j.inoche.2008.08.004

Reference yield: 89.0%

methanol (67-56-1) + 5,6-epoxy-5,6-dihydroxy-1,10-phenanthroline (65379-77-3) + [ytterbium(III)(5,10,15,20-tetraphenylphorphirin-2H)(acetate)(methanol)2] (1185986-66-6) → [Yb(5,10,15,20-tetraphenylporphyrinato)(η2-acetato)(5,6-epoxy-5,6-dihydroxy-1,10-phenanthroline)]*(methanol)*H2O

Guidance literature:

In toluene; ligand added to a soln. of Yb complex, stirred at room temp.; evapd. (vac.), dissolved in CH2Cl2, chromd. (silica gel, CH2Cl2), concd., MeOH added, filtered, dried (vac.); elem. anal.;

DOI:10.1039/b909243a

Reference yield: 86.0%

1,10-Phenanthroline (66-71-7) + [ytterbium(III)(5,10,15,20-tetraphenylphorphirin-2H)(acetate)(methanol)2] (1185986-66-6) → [Yb(5,10,15,20-tetraphenylporphyrinato)(η2-acetato)(1,10-phenanthroline)]*H2O

Guidance literature:

In toluene; ligand added to a soln. of Yb complex, stirred at room temp. for 12 h; evapd. (vac.), dissolved in CH2Cl2, chromd. (silica gel, CH2Cl2), concd., MeOH added, filtered, dried (vac., for 24 h); elem. anal.;

DOI:10.1039/b909243a

upstream raw materials:

methanol

5,10,15,20-tetraphenyl-21H,23H-porphine

Downstream raw materials:

[Yb(III)(5,10,15,20-tetraphenylporphyrinato-κ4N,N',N'',N''')(acetate)(5-(N,N-bis(3-(triethoxysilyl)propylcarbamoyl)amino)-1,10-phenanthroline)]