(η6-p-cymene)Ru(4-(dimethylamino)pyridine)(5-hydroxy-2-(hydroxymethyl)-4-pyrone)(tetrafluoroborate)

Base Information

• Chemical Name: (η6-p-cymene)Ru(4-(dimethylamino)pyridine)(5-hydroxy-2-(hydroxymethyl)-4-pyrone)(tetrafluoroborate)
• CAS No.: 1204169-71-0
• Molecular Formula: BF₄*C₆H₅O₄*C₇H₁₀N₂*C₁₀H₁₄*Ru
• Molecular Weight: 585.369
• Mol file: 1204169-71-0.mol

Synonyms:

Chemical Property of (η6-p-cymene)Ru(4-(dimethylamino)pyridine)(5-hydroxy-2-(hydroxymethyl)-4-pyrone)(tetrafluoroborate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η6-p-cymene)Ru(4-(dimethylamino)pyridine)(5-hydroxy-2-(hydroxymethyl)-4-pyrone)(tetrafluoroborate)

There total 1 articles about (η6-p-cymene)Ru(4-(dimethylamino)pyridine)(5-hydroxy-2-(hydroxymethyl)-4-pyrone)(tetrafluoroborate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

dmap (1122-58-3) + silver tetrafluoroborate (14104-20-2) + (η6-p-cymene)RuCl(5-hydroxy-2-(hydroxymethyl)-4-pyrone) (1164254-38-9) → (η6-p-cymene)Ru(4-(dimethylamino)pyridine)(5-hydroxy-2-(hydroxymethyl)-4-pyrone)(tetrafluoroborate) (1204169-71-0)

Guidance literature:

In acetone; byproducts: AgCl; Ru complex and AgBF4 suspended in acetone, stirred for 20 min; filtered,DMAP added, mixt. stirred for 3 h; filtered, solvent evapd. to dryness; residue dissolved in CH2Cl2; filtered through alumina bed; concd. to 3 ml, excess hexane added; washed withhexane, dried in vac.;

DOI:10.1016/j.ica.2009.09.006

upstream raw materials:

dmap

silver tetrafluoroborate

(η6-p-cymene)RuCl(5-hydroxy-2-(hydroxymethyl)-4-pyrone)