Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)Br(C₆H₄C₂C₆H₅)

Base Information

• Chemical Name: Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)Br(C₆H₄C₂C₆H₅)
• CAS No.: 1355198-34-3
• Molecular Formula: C₄₄H₅₁BrNOPPd
• Molecular Weight: 827.193
• Mol file: 1355198-34-3.mol

Synonyms:

Chemical Property of Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)Br(C₆H₄C₂C₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)Br(C₆H₄C₂C₆H₅)

There total 2 articles about Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)Br(C₆H₄C₂C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

allyl(cyclopentadiene)palladium(II) (1271-03-0) + N-(2-(di(1-adamantyl)phosphino)phenyl)morpholine (1237588-12-3) + 1-bromo-2-(phenylethenyl)benzene (21375-88-2) → Pd((NC4H8O)C6H4P(C10H15)2)Br(C6H4C2C6H5) (1355198-34-3)

Guidance literature:

In tetrahydrofuran; (N2, glovebox) the mixt. of complex, phosphine and ethynyl-compound in THF was sealed with a PTFE-lined cap, heated at 65°C for 16 h withstirring; concd. to dryness in vac., washed with diethyl ether, dried in vac.; elem. anal.;

DOI:10.1021/om201122q

Reference yield:

Pd((NC4H8O)C6H4P(C10H15)2)(C6H5C2C6H5) (1355198-40-1) + 1-bromo-2-(phenylethenyl)benzene (21375-88-2) → Pd((NC4H8O)C6H4P(C10H15)2)Br(C6H4C2C6H5) (1355198-34-3)

Guidance literature:

In tetrahydrofuran; (N2, glovebox) 1 equiv of ethynyl-compound, THF, at room temp. for 48 h or at 65°C for 2.5 h; detected by NMR spectra;

DOI:10.1021/om201122q

Reference yield: 83.0%

Pd((NC4H8O)C6H4P(C10H15)2)Br(C6H4C2C6H5) (1355198-34-3) + silver trifluoromethanesulfonate (2923-28-6) → Pd((NC4H8O)C6H4P(C10H15)2)(C6H4C2C6H5)(1+)*CF3SO3(1-)=Pd((NC4H8O)C6H4P(C10H15)2)(C6H4C2C6H5)CF3SO3 (1355198-38-7)

Guidance literature:

In dichloromethane; (N2, glovebox) AgOSO2CF3 was added to a soln. of complex in CH2Cl2, stirred for 1 h at room temp.; filtered, concd., dried in vac.; elem. anal.;

DOI:10.1021/om201122q

upstream raw materials:

allyl(cyclopentadiene)palladium(II)

N-(2-(di(1-adamantyl)phosphino)phenyl)morpholine

1-bromo-2-(phenylethenyl)benzene

Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₅C₂C₆H₅)

Downstream raw materials:

Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₄C₂C₆H₅)CF₃SO₃

Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)CF₃SO₃