Quinoline, 2,2'-(2,6-pyridinediyl)bis[4-phenyl-

Base Information

• Chemical Name: Quinoline, 2,2'-(2,6-pyridinediyl)bis[4-phenyl-
• CAS No.: 137731-79-4
• Molecular Formula: C₃₅H₂₃N₃
• Molecular Weight: 485.588
• DSSTox Substance ID: DTXSID50445583
• Nikkaji Number: J1.411.494G
• Wikidata: Q82264051
• Mol file: 137731-79-4.mol

Synonyms:137731-79-4;Quinoline, 2,2'-(2,6-pyridinediyl)bis[4-phenyl-;SCHEMBL22761530;DTXSID50445583;2,6-bis(4 -phenyl-2 -quinolyl)-pyridine;2,2'-(Pyridine-2,6-diyl)bis(4-phenylquinoline)

Chemical Property of Quinoline, 2,2'-(2,6-pyridinediyl)bis[4-phenyl-

Chemical Property:

• XLogP3: 8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 485.189197746
• Heavy Atom Count: 38
• Complexity: 682

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC(=NC3=CC=CC=C32)C4=NC(=CC=C4)C5=NC6=CC=CC=C6C(=C5)C7=CC=CC=C7

Technology Process of Quinoline, 2,2'-(2,6-pyridinediyl)bis[4-phenyl-

There total 1 articles about Quinoline, 2,2'-(2,6-pyridinediyl)bis[4-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2,6-Diacetylpyridine (1129-30-2) + (2-aminophenyl)(phenyl)methanone (2835-77-0) → 2,6-bis(4'-phenyl-2'-quinolinyl)pyridine (137731-79-4)

Guidance literature:

With phosphorus pentoxide; 3-methyl-phenol; at 145 ℃;

DOI:10.1039/DT9910002545

Reference yield: 57.0%

ammonium hexafluorophosphate + potassium aquapentachlororuthenate(III) + 2,6-bis(4'-phenyl-2'-quinolinyl)pyridine (137731-79-4) → Ru(C35H23N3)2(2+)*2PF6(1-)*H2O={Ru(C35H23N3)2}(PF6)2*H2O

Guidance literature:

In ethanol; glycerol; N2-atmosphere; addn. of ligand in glycerol/EtOH to glycerol soln. of Ru-complex (160°C), removal of EtOH, stirring (210°C, 24 h), water addn., refluxing (10 min), hot filtration, addn. of hot aq. NH4PF6 (pptn.); collection, washing (cold H2O, Et2O), gel filtration (Sephadex, EtOH), recrystn. (MeCN/Et2O); elem. anal.;

upstream raw materials:

2,6-Diacetylpyridine

(2-aminophenyl)(phenyl)methanone