bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc

Base Information

Chemical Name:bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc
CAS No.:916676-16-9
Molecular Formula:C₅₆H₆₂N₄O₁₄S₂Zn
Molecular Weight:1144.65
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc

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Technology Process of bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc

There total 2 articles about bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 6590-65-4
N-(2-Formyl-phenyl)-4-methyl-benzenesulfonamide

: 60835-71-4
4'-aminobenzo-15-crown-5-ether

: 5970-45-6
zinc(II) acetate dihydrate

: 916676-16-9
bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc

Guidance literature:: In methanol; addn. of soln. of 4-aminobenzo-15-crown-5 in MeOH to soln. of 2-(tosylamino)benzaldehyde in MeOH; reflux for 1 h; addn. of soln. of Zn(CH3COO)2*2H2O; reflux for 1 h; cooling, pptn.; filtration, washing with MeOH; recrystn. from MeOH-CHCl3(2:1); drying in vac. oven at 150°C; elem. anal.;
DOI:10.1134/S1070363206060259

Reference yield:

: 871810-44-5
4'-[2-(tosylamino)benzylideneamino]-2,3-benzo-15-crown-5

: 557-34-6
zinc diacetate

: 916676-16-9
bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc

Guidance literature:: In methanol; Zn salt added to ligand in CH3OH, refluxed for 2 h; filtered, recrystd.(alcohol), elem. anal.;
DOI:10.1134/S107032840603002X

Reference yield:

: 916676-16-9
bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc

: 7732-18-5
water

: lithium perchlorate

: 2LiClO4*[zinc N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate]*2H2O

Guidance literature:: In acetonitrile; dissolving of zinc N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate (ZnL2) in acetonitrile; addn. of LiClO4 in ratio ZnL2:Li=1:2; standing in air for 5 - 7 ds; evapn. of solvent; washing with alcohol and drying over CaCl2; elem. anal.;
DOI:10.1134/S0036023607110125