HRu(CO)4SnPh₃

Base Information

Chemical Name:HRu(CO)4SnPh₃
CAS No.:944391-10-0
Molecular Formula:C₂₂H₁₆O₄RuSn
Molecular Weight:564.147
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of HRu(CO)4SnPh₃

Chemical Property:

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Technology Process of HRu(CO)4SnPh₃

There total 1 articles about HRu(CO)4SnPh₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 201230-82-2
carbon monoxide

: 892-20-6
triphenylstannane

: 944391-10-0
HRu(CO)4SnPh₃

Guidance literature:: In benzene; Irradiation (UV/VIS); under N2 atm. soln. Ru3(CO)12 in hexane was placed in ice bath and irradiated with medium-pressure mercury UV lamp (1000 W) inthe presence CO slow purge for 25 min, CO was removed with N2, HSnPh3 was added at 0°C, heated to reflux for 10 min; react. mixt. was cooled, solvent was removed in vacuo, TLC (hexane-CH2Cl2 6:1); elem. anal.;
DOI:10.1021/ja070617h

Reference yield: 33.0%

: 60648-70-6
bis(tri-tert-butylphosphine)platinum⁽⁰⁾

: 944391-10-0
HRu(CO)4SnPh₃

: 536-74-3
phenylacetylene

: 944391-17-7
PtRu(CO)4(SnPh3)(PBu(t)3)[μ-H2CCPh]

: PtRu(CO)4(SnPh3)(PBu(t)3)[μ-HCC(H)Ph]*3/2C6H6

Guidance literature:: In dichloromethane; under N2 atm. to soln. Pt complexes in CH2Cl2 PhCCH was added and heatedto reflux for 20 min, Ru-Sn complex was added and refluxed for 10 min; solvent was removed in vacuo, TLC (hexane-CH2Cl2 6:1); elem. anal.;
DOI:10.1021/ja070617h

Reference yield: 15.0%

: 53199-31-8
bis(tri-t-butylphosphine)palladium⁽⁰⁾

: 944391-10-0
HRu(CO)4SnPh₃

: 536-74-3
phenylacetylene

: PdRu(CO)4(SnPh3)(PBu(t)3)[μ-H2CCPh]

Guidance literature:: In dichloromethane; under N2 atm. to soln. Pd complexes in CH2Cl2 PhCCH was added and heatedto reflux for 20 min, Ru-Sn complex was added and refluxed for 10 min; solvent was removed in vacuo, TLC (hexane-CH2Cl2 6:1); elem. anal.;
DOI:10.1021/ja070617h