(1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate

Base Information

• Chemical Name: (1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate
• CAS No.: 933445-78-4
• Molecular Formula: C₁₉H₃₃N₄S₃Zn*ClO₄
• Molecular Weight: 578.536
• Mol file: 933445-78-4.mol

Synonyms:

Chemical Property of (1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate

There total 1 articles about (1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

carbon disulfide (75-15-0,12122-00-8) + (1,4,8,12-tetraazacyclopentadecane)zinc(II) benzylthiolate perchlorate (933778-31-5,906005-45-6) → (1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate (933445-78-4)

Guidance literature:

In dichloromethane; Zn complex in CH2Cl2 treated with CS2; crystd., separated, washed (CS2), elem. anal.;

DOI:10.1002/ejic.200500948

Reference yield: 76.0%

(1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate (933445-78-4) + methyl iodide (74-88-4) → (1,4,8,12-tetraazacyclopentadecane)zinc(II) iodide perchlorate + benzyl methyl trithiocarbonate (82843-64-9)

Guidance literature:

In chloroform; byproducts: benzyl methyl sulfide; CS2 added to Zn complex in CHCl3, reacted for 30 min, treated with CH3I,stirred overnight; evapd., washed (pentane), concd., chromy.(silica - pentane), elem. anal., NMR;

DOI:10.1002/ejic.200500948

Reference yield: 72.0%

(1,4,8,12-tetraazacyclopentadecane)zinc(II) benzyltrithiocarbonate perchlorate (933445-78-4) + acetyl chloride (75-36-5) → benzyl acetyl trithiocarbonate + (1,4,8,12-tetraazacyclopentadecane)zinc(II) chloride perchlorate (209070-28-0)

Guidance literature:

In chloroform; CS2 added to Zn complex in CHCl3, reacted for 30 min, treated with CH3I,stirred for 20 min; chromy.(silica - CHCl3), elem. anal., NMR;

DOI:10.1002/ejic.200500948

upstream raw materials:

carbon disulfide

(1,4,8,12-tetraazacyclopentadecane)zinc(II) benzylthiolate perchlorate

Downstream raw materials:

benzyl methyl trithiocarbonate

(1,4,8,12-tetraazacyclopentadecane)zinc(II) chloride perchlorate