Re(CO)3(tricyclohexylphosphine)2Cl

Base Information

• Chemical Name: Re(CO)3(tricyclohexylphosphine)2Cl
• CAS No.: 85848-25-5
• Molecular Formula: C₃₉H₆₆ClO₃P₂Re
• Molecular Weight: 866.559
• Mol file: 85848-25-5.mol

Synonyms:

Chemical Property of Re(CO)3(tricyclohexylphosphine)2Cl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Re(CO)3(tricyclohexylphosphine)2Cl

There total 1 articles about Re(CO)3(tricyclohexylphosphine)2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Re2(CO)8(tricyclohexylphosphine)2 (65531-96-6) + tricyclohexylphosphine (2622-14-2) → Re(CO)3(tricyclohexylphosphine)2Cl (85848-25-5)

Guidance literature:

With tetrachloromethane; In benzene; Irradiation (UV/VIS); soln. of complex and ligand irradiated for 5 h (soln. occasionally degassed), CCl4 added; not isolated, detected by IR;

DOI:10.1021/om00078a018

Reference yield:

Re(CO)3(P(C6H11)3)2Cl (85848-25-5) + hydrogen (1333-74-0) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [trans-mer-Re(H2)(PCy3)2(CO)3][B(3,5-(CF3)2C6H3)4] (155963-05-6)

Guidance literature:

In dichloromethane; (H2); air and moisture exclusion; 24 h, room temp.;

DOI:10.1021/ja9643228

upstream raw materials:

Re₂(CO)8(tricyclohexylphosphine)2

tricyclohexylphosphine

Downstream raw materials:

[trans-mer-Re(H₂)(PCy₃)2(CO)3][B(3,5-(CF₃)2C₆H₃)4]