Trifluorovinylbis(trifluoromethyl)amine

Base Information

• Chemical Name: Trifluorovinylbis(trifluoromethyl)amine
• CAS No.: 13821-49-3
• Molecular Formula: C4F9N
• Molecular Weight: 233.036
• DSSTox Substance ID: DTXSID00436921
• Nikkaji Number: J801.229F
• Mol file: 13821-49-3.mol

Synonyms:Trifluorovinylbis(trifluoromethyl)amine;13821-49-3;1,2,2-trifluoro-N,N-bis(trifluoromethyl)ethenamine;SCHEMBL8921052;DTXSID00436921;WZASSYDMYUZHRC-UHFFFAOYSA-N;perfluoro[N,N-dimethyl(vinylamine)];1,2,2-trifluoro-N,N-bis(trifluoromethyl)-ethenamine

Chemical Property of Trifluorovinylbis(trifluoromethyl)amine

Chemical Property:

• Boiling Point: 11.11°C (rough estimate)
• PSA: 3.24000
• LogP: 3.36310
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 1
• Exact Mass: 232.98870246
• Heavy Atom Count: 14
• Complexity: 216

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(F)F)(N(C(F)(F)F)C(F)(F)F)F

Technology Process of Trifluorovinylbis(trifluoromethyl)amine

There total 1 articles about Trifluorovinylbis(trifluoromethyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

perfluoro(dimethyl-2-methoxybutylamine) (17636-84-9) → perfluoropropanoyl fluoride (422-61-7) + trifluoromethyl trifluorovinyl ether (1187-93-5) + perfluoro(2-aza-2-pentene) (680-23-9) + perfluoro(N,N-dimethyl trifluorovinylamine) (13821-49-3)

Guidance literature:

platinum; at 590 ℃; Further byproducts given;

DOI:10.1039/j39680000398

Reference yield: 46.0%

perfluoro(N,N-dimethyl trifluorovinylamine) (13821-49-3) → trifluoromethan (75-46-7) + Vinylidene fluoride (75-38-7) + Hexafluoroethane (76-16-4) + trifluoromethyl isocyanate (460-49-1) + perfluoro(2-aza-1-hexene) (559-93-3)

Guidance literature:

With toluene; pyrolysis 610°C, contact time 0.66 sec, further product;

Reference yield:

perfluoro(N,N-dimethyl trifluorovinylamine) (13821-49-3) → Carbonyl fluoride (353-50-4) + Hexafluoroethane (76-16-4) + trifluoromethyl isocyanate (460-49-1) + silicon tetrafluoride (7783-61-1)

Guidance literature:

pyrolysis in Pt tube at 1-2 Torr, 595°C, contact time 1.1 sec, 92% of starting material is recovered undecomposed;

upstream raw materials:

perfluoro(dimethyl-2-methoxybutylamine)

Downstream raw materials:

trifluoromethan

Vinylidene fluoride

Hexafluoroethane

trifluoromethyl isocyanate