[Ru(CO)2(P(C₆H₅)3)(CH₂C(CH₃)C(CH₃)CH₂)]

Base Information

• Chemical Name: [Ru(CO)2(P(C₆H₅)3)(CH₂C(CH₃)C(CH₃)CH₂)]
• CAS No.: 75826-70-9
• Molecular Formula: C₂₆H₂₅O₂PRu
• Molecular Weight: 501.527
• Mol file: 75826-70-9.mol

Synonyms:

Chemical Property of [Ru(CO)2(P(C₆H₅)3)(CH₂C(CH₃)C(CH₃)CH₂)]

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of [Ru(CO)2(P(C₆H₅)3)(CH₂C(CH₃)C(CH₃)CH₂)]

There total 1 articles about [Ru(CO)2(P(C₆H₅)3)(CH₂C(CH₃)C(CH₃)CH₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → Ru(CO)3(η(4)-2,3-dimethylbutadiene) (52649-53-3) + [Ru(CO)2(P(C6H5)3)(CH2C(CH3)C(CH3)CH2)] (75826-70-9)

Guidance literature:

With triphenylphosphine; In n-heptane; (N2); mixt. of complex and 2,3-dimethylbuta-1,3-diene in heptane refluxed for 20 h, PPh3 added, heated for 3 d; solvent removed in vac., residue dissolved in CH2Cl2, chromd. (Al2O3, hexane, then hexane/Et2O), solvent removed, dissolved in CH2Cl2, filtered, hexane added, concd.; elem. anal.;

Reference yield: 88.0%

o-tetrachloroquinone (2435-53-2) + [Ru(CO)2(P(C6H5)3)(CH2C(CH3)C(CH3)CH2)] (75826-70-9) → ((ruthenium(carbonyl)2(PPh3)(μ-o-O2C6Cl4))2)

Guidance literature:

In dichloromethane; (N2); C6Cl4O2 added to stirred complex soln., reacted for 15 min; filtered, pptd. (hexane), washed (hexane), dissolved in CH2Cl2, filtered, hexane added, concd.; elem. anal.;

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

2,3-dimethyl-buta-1,3-diene

Refernces