chlorine perchlorate

Base Information

• Chemical Name: chlorine perchlorate
• CAS No.: 193404-47-6
• Molecular Formula: Cl₂O₄
• Molecular Weight: 134.904
• Mol file: 193404-47-6.mol

Synonyms:

Chemical Property of chlorine perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorine perchlorate

There total 3 articles about chlorine perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

chlorine dioxide (10049-04-4,25052-55-5) → chlorine trioxide (13932-10-0) + chlorine perchlorate (193404-47-6,27218-16-2) + dichlorine hexoxide + chlorine (7782-50-5)

Guidance literature:

In gas; Irradiation (UV/VIS); ClO2 at 100 Torr and 30°C is photolyzed with λ=436 nm until it is practically completely consumed; condensation at -35°C to remove ClO3 and Cl2O6; fractionated condensation at -100°C removes Cl2 and at -60°C residual ClO2; purity checked by IR spectroscopy;

Reference yield:

dichlorine hexaoxide (12442-63-6) → chlorine perchlorate (193404-47-6,27218-16-2) + chlorine dioxide (10049-04-4,25052-55-5)

Guidance literature:

In neat (no solvent); byproducts: O2; decompn. in dry state at room temp. (pressure 1 mbar, half-life ca 8 min);

Reference yield:

dichlorine hexaoxide (12442-63-6) + antimonypentachloride (7647-18-9) → chlorine perchlorate (193404-47-6,27218-16-2) + perchloric anhydride (12015-53-1) + Sb8Cl24O5(ClO4)6 (82135-08-8) + chlorine dioxide (10049-04-4,25052-55-5)

Guidance literature:

In neat (no solvent); byproducts: Cl2; Cl2O6 added to SbCl5 at -180°C in Pyrex reactor, mixt. allowed to warm slowly to 10°C, gases removed periodically; unreacted SbCl5 pumped out, elem. anal.;

upstream raw materials:

chlorine dioxide

dichlorine hexaoxide

antimonypentachloride

Downstream raw materials:

chlorine dioxide

Refernces

• 1、 Belin,Chaabouni,Pascal,Potier. "Two new perchlorato complexes. The oxochloro(perchlorato)antimony complexes Sb2Cl6(OH)(O)(ClO4) and Sb8Cl24(O5)(ClO4)6: Synthesis, vibrational spectroscopy, and X-ray ". . p. 3557 - 3560. Retrieved 2008/10/08.