(triphenylphosphine)3RhH₂Cl

Base Information

• Chemical Name: (triphenylphosphine)3RhH₂Cl
• CAS No.: 93860-48-1
• Molecular Formula: C₅₄H₄₇ClP₃Rh
• Molecular Weight: 927.247
• Mol file: 93860-48-1.mol

Synonyms:

Chemical Property of (triphenylphosphine)3RhH₂Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (triphenylphosphine)3RhH₂Cl

There total 6 articles about (triphenylphosphine)3RhH₂Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydridotris(triphenylphosphine)rhodium (16973-49-2) + LINDANE (58-89-9,6108-11-8,8073-23-2) → Wilkinson's catalyst (14694-95-2) + [rhodium(I)chloride(triphenylphosphine)2]1 (14653-50-0) + (triphenylphosphine)3RhH2Cl (93860-48-1,17949-78-9)

Guidance literature:

In benzene-d6; byproducts: C6H5Cl5; identified by NMR;

DOI:10.1021/om049786q

Reference yield:

Wilkinson's catalyst (14694-95-2) + (1-hexyl)(hexyl)silane (1002-78-4) → hydridotetakis(triphenylphosphine)rhodium(I) (18284-36-1,27497-56-9) + hydridotris(triphenylphosphine)rhodium (16973-49-2) + (triphenylphosphine)3RhH2Cl (93860-48-1,17949-78-9) + Rh(P(C6H5)3)2(H)(Cl)(SiH(C6H13)2) (892546-68-8)

Guidance literature:

In ⁽²⁾H₈-toluene; at 210 K; not isolated; detd. by (14)P NMR;

DOI:10.1002/ejic.201001165

Reference yield:

triethylsilane (617-86-7) + Wilkinson's catalyst (14694-95-2) → (triphenylphosphine)3RhH2Cl (93860-48-1,17949-78-9)

Guidance literature:

With γ-C6H6Cl6; In ⁽²⁾H₈-toluene; under inert atm. suspn. RhCl(PPh3)3,γ-C6H6Cl6, and HSiEt3 in toluene-d8 was heated at 70°C for 10 min; identified by NMR;

DOI:10.1021/om049786q

upstream raw materials:

triethylsilane

Wilkinson's catalyst

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

hydridotris(triphenylphosphine)rhodium

Downstream raw materials:

Wilkinson's catalyst