{Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)={Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}(ClO₄)2

Base Information

• Chemical Name: {Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)={Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}(ClO₄)2
• CAS No.: 110903-83-8
• Molecular Formula: C₆₀H₉₀Hg₄P₄Se₆*2ClO₄
• Molecular Weight: 2410.29
• Mol file: 110903-83-8.mol

Synonyms:

Chemical Property of {Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)={Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}(ClO₄)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)={Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}(ClO₄)2

There total 1 articles about {Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)={Hg₄(SeC₆H₅)6(P(C₂H₅)3)4}(ClO₄)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

Hg(2+)*2P(C2H5)3*2ClO4(1-)=Hg(P(C2H5)3)2(ClO4)2 (110904-30-8) + di(phenylselenenyl)mercury (21514-25-0) + triethylphosphine (554-70-1) → {Hg4(SeC6H5)6(P(C2H5)3)4}(2+)*2ClO4(1-)={Hg4(SeC6H5)6(P(C2H5)3)4}(ClO4)2 (110903-83-8)

Guidance literature:

In chloroform; addn. of solid Hg(SeC6H5)2 to soln. of Hg(P(C2H5)3)2(ClO4)2) and P(C2H5)3 in CHCl3 with stirring ; removing solvent after 10 min (Ar); dissolving in acetone; filtering and cooling to 0°C; addn. of (C2H5)2O; storing overnight at 0°C;; crystn.; decanting, washing with diethylether and drying in vac.; elem. anal.;;

Reference yield: 52.0%

(4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II) + {Hg4(SeC6H5)6(P(C2H5)3)4}(2+)*2ClO4(1-)={Hg4(SeC6H5)6(P(C2H5)3)4}(ClO4)2 (110903-83-8) + dichloromethane (75-09-2) → [PtMe2(SePh)(PEt3)(4,4'-di-tert-butyl-2,2'-bipyridine)](ClO4)*CH2Cl2 (440114-93-2)

Guidance literature:

In dichloromethane; byproducts: Hg, Hg(SePh)2(PEt3); dissolving of mixt. of PtMe2(((CH3)3CC5H3N)2) and (Hg4(SePh)6(PEt3)4)(ClO4)2 in CH2Cl2, stirring for 10 min; filtration through dry Celite, addn. of pentane, pptn., filtration, washing with pentane, drying in vac., elem. anal.;

DOI:10.1139/v01-187

upstream raw materials:

Hg⁽²⁺⁾*2P(C₂H₅)3*2ClO₄^(1-)=Hg(P(C₂H₅)3)2(ClO₄)2

di(phenylselenenyl)mercury

triethylphosphine

Downstream raw materials:

[PtMe₂(SePh)(PEt₃)(4,4'-di-tert-butyl-2,2'-bipyridine)](ClO₄)*CH₂Cl₂